Boosting photocatalytic hydrogen evolution of g-C3N4 catalyst via lowering the Fermi level of co-catalyst

The photocatalytic performances are highly dependent on the charge separation and surface reaction kinetics of photocatalysts. Aiming at figuring out the effects of co-catalyst with the lower Fermi level on photocatalytic activity, we tuned the Fermi level of Pt nanoparticles on g-C3N4(GCN) by introducing Co atom. Experimental results show that lowering the Fermi level of co-catalyst does not alter light absorption of GCN due to the invariable structure. Besides, Pt3Co with a lower Fermi level contributes less positive influence on charge separation in GCN due to an opposite effect from the stronger electron-trap ability of Pt3Co and increased band bending in GCN-Pt3Co. The density functional theory (DFT) calculations indicate that GCN-Pt3Co has faster surface reaction kinetics than GCN-Pt, owing to easier dissociation of H2O molecules and faster desorption of H* on Pt3Co. Consequently, GCN-Pt3Co exhibits an excellent H-2 evolution rate with 2.91 mmol center dot g(-1)center dot h(-1), which 2.67 times that of GCN-Pt.