Platinum-assisted preparation of PS ligands containing chiral centres; X-ray crystal structure of a dithiophosphinite platinum complex

被引：4

作者：

Bergamini, P

Bertolasi, V

Giordani, R

机构：

[1] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy

[2] Univ Ferrara, Ctr Strutturist Diffrattometr, I-44100 Ferrara, Italy

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 06期

关键词：

ligand design; P ligands; platinum; asymmetric catalyst;

D O I：

10.1016/j.ica.2004.12.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The design and synthesis of some ligands containing P(111) bonded to sulfur (thiophosphinites) and chiral centres is described in this paper. Their complexes with platinum (II), [PtCl2L], (L = bidentate dithiophosphinite) have been prepared and characterised and it has been shown that in many cases, the coordination to platinum protects these ligands from decomposition processes operated by moisture and oxygen. The first example of X-ray crystal structure of a platinum coordinated dithiophosphinite is described for complex cis-[PtCl2L], [L = meso-2,3-bis(diphenylthiophosphinito)-dimethyl-succinate], 4a. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2031 / 2039

页数：9

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