Direct Hydrogenation of a Broad Range of Amides under Base-free Conditions using an Efficient and Selective Ruthenium(II) Pincer Catalyst

被引：28
|
作者：
Wang, Zheng [1 ,2 ,3 ,4 ]
Li, Yong [1 ]
Liu, Qing-bin [1 ]
Solan, Gregory A. [2 ,3 ,5 ]
Ma, Yanping [2 ,3 ]
Sun, Wen-Hua [2 ,3 ,4 ]
机构：
[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Hebei, Peoples R China
[2] Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
[4] Univ Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100049, Peoples R China
[5] Univ Leicester, Dept Chem, Univ Rd, Leicester LE1 7RH, Leics, England
来源：
CHEMCATCHEM | 2017年 / 9卷 / 22期
基金：
中国国家自然科学基金;
关键词：
amides; amines; homogeneous catalysis; hydrogenation; ruthenium; METAL-LIGAND COOPERATION; HOMOGENEOUS HYDROGENATION; SECONDARY ALCOHOLS; TERTIARY AMIDES; MILD CONDITIONS; AMINES; REDUCTION; COMPLEX; ACID; DEHYDROGENATION;
D O I：
10.1002/cctc.201700952
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ruthenium(II) complex, [fac-PNHN]RuH((1)-BH4)(CO) (B; PNHN=8-(2-diphenylphosphinoethyl)aminotrihydroquinoline), is a highly versatile and effective catalyst (loadings of 0.1-1mol%) for the hydrogenation of a multitude of amides, which include primary, secondary, and tertiary amides, to give their corresponding alcohols and amines in high yields under base-free conditions. All products were confirmed by using GC and GC-MS.
引用
收藏
页码：4275 / 4281
页数：7
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