Direct Hydrogenation of a Broad Range of Amides under Base-free Conditions using an Efficient and Selective Ruthenium(II) Pincer Catalyst

被引：28

作者：

Wang, Zheng ^{[1
,2
,3
,4
]}

Li, Yong ^{[1
]}

Liu, Qing-bin ^{[1
]}

Solan, Gregory A. ^{[2
,3
,5
]}

Ma, Yanping ^{[2
,3
]}

Sun, Wen-Hua ^{[2
,3
,4
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Hebei, Peoples R China

[2] Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China

[3] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China

[4] Univ Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100049, Peoples R China

[5] Univ Leicester, Dept Chem, Univ Rd, Leicester LE1 7RH, Leics, England

来源：

CHEMCATCHEM | 2017年 / 9卷 / 22期

基金：

中国国家自然科学基金;

关键词：

amides; amines; homogeneous catalysis; hydrogenation; ruthenium; METAL-LIGAND COOPERATION; HOMOGENEOUS HYDROGENATION; SECONDARY ALCOHOLS; TERTIARY AMIDES; MILD CONDITIONS; AMINES; REDUCTION; COMPLEX; ACID; DEHYDROGENATION;

D O I：

10.1002/cctc.201700952

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ruthenium(II) complex, [fac-PNHN]RuH((1)-BH4)(CO) (B; PNHN=8-(2-diphenylphosphinoethyl)aminotrihydroquinoline), is a highly versatile and effective catalyst (loadings of 0.1-1mol%) for the hydrogenation of a multitude of amides, which include primary, secondary, and tertiary amides, to give their corresponding alcohols and amines in high yields under base-free conditions. All products were confirmed by using GC and GC-MS.

引用

页码：4275 / 4281

页数：7

共 50 条

[31] Base-Free Methanol Dehydrogenation Using a Pincer-Supported Iron Compound and Lewis Acid Co-catalyst
Bielinski, Elizabeth A.
Foerster, Moritz
Zhang, Yuanyuan
Bernskoetter, Wesley H.
Hazari, Nilay
Holthausen, Max C.
ACS CATALYSIS, 2015, 5 (04): : 2404 - 2415
[32] Selective Base-free Transfer Hydrogenation of ,-Unsaturated Carbonyl Compounds using iPrOH or EtOH as Hydrogen Source
Farrar-Tobar, Ronald A.
Wei, Zhihong
Jiao, Haijun
Hinze, Sandra
de Vries, Johannes G.
CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (11) : 2725 - 2734
[33] Selective Oxidation of n-Butanol Using Gold-Palladium Supported Nanoparticles Under Base-Free Conditions
Gandarias, Inaki
Miedziak, Peter J.
Nowicka, Ewa
Douthwaite, Mark
Morgan, David J.
Hutchings, Graham J.
Taylor, Stuart H.
CHEMSUSCHEM, 2015, 8 (03) : 473 - 480
[34] Noninnocent Ligands for Efficient Dehydrogenation of Aqueous and Neat Formic Acid under Base-Free Conditions
Guo, Liwei
Li, Zilong
Cordier, Marie
Marchal, Remi
Le Guennic, Boris
Fischmeister, Cedric
ACS CATALYSIS, 2023, 13 (20) : 13626 - 13637
[35] AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditions
Bonincontro, Danao
Lolli, Alice
Villa, Alberto
Prati, Laura
Dimitratos, Nikolaos
Veith, Gabriel M.
Chinchilla, Lidia E.
Botton, Gianlugi A.
Cavani, Fabrizio
Albonetti, Stefania
GREEN CHEMISTRY, 2019, 21 (15) : 4090 - 4099
[36] Acylation/cyclization of 1,6-dienes with ethers under catalyst- and base-free conditions
Huang, Xun-Jie
Qin, Fu-Hua
Liu, Yi
Wu, Shi-Ping
Li, Qiang
Wei, Wen-Ting
GREEN CHEMISTRY, 2020, 22 (12) : 3952 - 3955
[37] Base-Free Suzuki–Miyaura Coupling Reaction Using Palladium(II) Supported Catalyst in Water
Ravi Tomar
Nidhi Singh
Neeraj Kumar
Vartika Tomar
Ramesh Chandra
Catalysis Letters, 2019, 149 : 1589 - 1594
[38] Ruthenium Complexes of Triazole-Based Scorpionate Ligands Transfer Hydrogen to Substrates under Base-Free Conditions
Kumar, Mukesh
DePasquale, Joseph
White, Nicholas J.
Zeller, Matthias
Papish, Elizabeth T.
ORGANOMETALLICS, 2013, 32 (07) : 2135 - 2144
[39] Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex
Papa, Veronica
Cabrero-Antonino, Jose R.
Alberico, Elisabetta
Spanneberg, Anke
Junge, Kathrin
Junge, Henrik
Beller, Matthias
CHEMICAL SCIENCE, 2017, 8 (05) : 3576 - 3585
[40] Oxidation of Glucose Using Mono- and Bimetallic Catalysts under Base-Free Conditions
Shi, Honghong
Thapa, Prem S.
Subramaniam, Bala
Chaudhari, Raghunath V.
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2018, 22 (12) : 1653 - 1662

← 1 2 3 4 5 →