Pd-Catalyzed Direct C-H Bond Sulfonylation of Azobenzenes with Arylsulfonyl Chlorides

被引：94

作者：

Zhang, Duo ^{[1
]}

Cui, Xiuling ^{[1
,2
,3
]}

Zhang, Qianqian ^{[1
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Dept Chem, Zhengzhou 450052, Peoples R China

[2] Huaqiao Univ, Inst Mol Med, Sch Biomed Sci, Xiamen Key Lab Ocean & Gene Drugs, Xiamen 361021, Fujian, Peoples R China

[3] Chinese Educ Minist, Engn Res Ctr Mol Med, Xiamen 361021, Fujian, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 03期

基金：

中国国家自然科学基金;

关键词：

HETEROCYCLIC AZO DYESTUFFS; ANALYTICAL-CHEMISTRY; EFFICIENT SYNTHESIS; HUMAN ANGIOGENIN; ORTHO-ACYLATION; SULFONES; ARYL; INHIBITORS; ARYLATION; OXIDATION;

D O I：

10.1021/jo502451k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pd(II)-catalyzed C-H sulfonylation of azobenzenes with arylsulfonyl chlorides has been developed. The sulfonylazobenzenes were obtained in moderate to excellent yields for 28 examples. This protocol features high efficiency, wide functional group tolerance, and atom economy.

引用

页码：1517 / 1522

页数：6

共 52 条

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