Fabrication of Bi2MoO6 nanoplates hybridized with g-C3N4 nanosheets as highly efficient visible light responsive heterojunction photocatalysts for Rhodamine B degradation

被引：67

作者：

Chen, Wei ^{[1
]}

Duan, Guo-Rong ^{[1
]}

Liu, Tian-Yu ^{[1
]}

Chen, Shen-Ming ^{[2
]}

Liu, Xiao-Heng ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Key Lab Educ, Minist Soft Chem & Funct Mat, Nanjing 210094, Jiangsu, Peoples R China

[2] Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Electroanal & Bioelectrochem Lab, Taipei 106, Taiwan

来源：

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING | 2015年 / 35卷

基金：

中国国家自然科学基金;

关键词：

Heterojunction photocatalyst; g-C3N4; Visible light; Bi2MoO6; nanoplates; IN-SITU SYNTHESIS; COMPOSITE PHOTOCATALYSTS; SOLVOTHERMAL SYNTHESIS; CONTROLLABLE SYNTHESIS; METHYL-ORANGE; PERFORMANCE; PHOTODEGRADATION; ENHANCEMENT; MORPHOLOGY; EVOLUTION;

D O I：

10.1016/j.mssp.2015.02.072

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

The Bi2MoO6/g-C3N4 heterojunction photocatalysts have been successfully fabricated using a simple liquid chemisorptions and thermal post-treatment. These nanostructured Bi2MoO6/g-C3N4 composites were extensively characterized by X-ray diffraction(XRD), field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR),UV-vis diffuse reflectance spectra (UV-vis DRS) and Photoluminescence (PL). The photocatalytic results show that 20 wt% Bi2MoO6/g-C3N4 sample exhibits efficient visible light activity and excellent photo-stability. The kinetic constant of RhB degradation over 20 wt% Bi2MoO6/g-C3N4 is about 5 and 2.5 times higher than that over pure Bi2MoO6 and g-C3N4 nanosheets, respectively. The enhanced photocatalytic performance is attributed to the construction of heterogeneous interface to promote photo-induced charge carrier pairs separation. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：45 / 54

页数：10

共 45 条

[1] Enhancement of visible photocatalytic activity via Ag@C3N4 core-shell plasmonic composite [J].

Bai, Xiaojuan ;

Zong, Ruilong ;

Li, Cuixia ;

Liu, Di ;

Liu, Yanfang ;

Zhu, Yongfa .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 147 :82-91

[2] Effects of the solvent on the structure, morphology and photocatalytic properties of Bi2MoO6 in the solvothermal process [J].

Bi, Jinhong ;

Che, Jiangang ;

Wu, Ling ;

Liu, Minghua .

MATERIALS RESEARCH BULLETIN, 2013, 48 (06) :2071-2075

[3] Enhanced visible-light photocatalytic activity of g-C3N4/TiO2 films [J].

Boonprakob, Natkritta ;

Wetchakun, Natda ;

Phanichphant, Sukon ;

Waxler, David ;

Sherrell, Peter ;

Nattestad, Andrew ;

Chen, Jun ;

Inceesungvorn, Burapat .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 417 :402-409

[4] Novel Mesoporous Graphite Carbon Nitride/BiOI Heterojunction for Enhancing Photocatalytic Performance Under Visible-Light Irradiation [J].

Chang, Chun ;

Zhu, Lingyan ;

Wang, Shanfeng ;

Chu, Xiaolong ;

Yue, Longfei .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (07) :5083-5093

[5] Enhanced photocatalytic performance of g-C3N4 nanosheets-BiOBr hybrids [J].

Chang, Fei ;

Li, Chenlu ;

Chen, Juan ;

Wang, Jie ;

Luo, Peru ;

Xie, Yunchao ;

Deng, Baoqing ;

Hu, Xuefeng .

SUPERLATTICES AND MICROSTRUCTURES, 2014, 76 :90-104

[6] Fabrication of highly visible light sensitive graphite-like C3N4 hybridized with Zn0.28Cd0.72S heterjunctions photocatalyst for degradation of organic pollutants [J].

Chen, Wei ;

Chen, Zhouli ;

Liu, Tianyu ;

Jia, Zhimin ;

Liu, Xiaoheng .

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2014, 2 (03) :1889-1897

[7] Heterojunction of facet coupled g-C3N4/surface-fluorinated TiO2 nanosheets for organic pollutants degradation under visible LED light irradiation [J].

Dai, Kai ;

Lu, Luhua ;

Liang, Changhao ;

Liu, Qi ;

Zhu, Guangping .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 156 :331-340

[8] Coupled systems for selective oxidation of aromatic alcohols to aldehydes and reduction of nitrobenzene into aniline using CdS/g-C3N4 photocatalyst under visible light irradiation [J].

Dai, Xia ;

Xie, Mengli ;

Meng, Sugang ;

Fu, Xianliang ;

Chen, Shifu .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 158 :382-390

[9] Visible-light enhancement of methylene blue photodegradation by graphitic carbon nitride-titania composites [J].

Fu, Dongying ;

Han, Gaoyi ;

Liu, Feifei ;

Xiao, Yaoming ;

Wang, Hongfei ;

Liu, Ruiqin ;

Liu, Cuixian .

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2014, 27 :966-974

[10] Synthesis and Efficient Visible Light Photocatalytic Hydrogen Evolution of Polymeric g-C3N4 Coupled with CdS Quantum Dots [J].

Ge, Lei ;

Zuo, Fan ;

Liu, Jikai ;

Ma, Quan ;

Wang, Chen ;

Sun, Dezheng ;

Bartels, Ludwig ;

Feng, Pingyun .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (25) :13708-13714

← 1 2 3 4 5 →