Synthesis of chiral bis-thiazolines and asymmetric Diels-Alder reactions

被引:15
作者
Nishio, T [1 ]
Kodama, Y
Tsurumi, Y
机构
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
[2] Univ Tsukuba, Grad Sch Environm Sci, Tsukuba, Ibaraki 3058571, Japan
关键词
asymmetric catalyst; bis-(N-acylamino) alcohol; chiral bis-thiazoline; Diels-Alder reaction; Lawesson's reagent;
D O I
10.1080/10426500590913032
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New chiral ligands, bis-thiazoline derivatives (sulfur analogues of known oxazolines) were prepared from chiral bis-(N-acylamino alcohols) with Lawesson's reagent. Bis-thiazolines thus obtained proved to be useful chiral ligands for metal in asymmetric Diels-Alder reaction.
引用
收藏
页码:1449 / 1450
页数:2
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