Synthesis of chiral bis-thiazolines and asymmetric Diels-Alder reactions

被引：15

作者：

Nishio, T ^{[1
]}

Kodama, Y

Tsurumi, Y

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

[2] Univ Tsukuba, Grad Sch Environm Sci, Tsukuba, Ibaraki 3058571, Japan

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2005年 / 180卷 / 5-6期

关键词：

asymmetric catalyst; bis-(N-acylamino) alcohol; chiral bis-thiazoline; Diels-Alder reaction; Lawesson's reagent;

D O I：

10.1080/10426500590913032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New chiral ligands, bis-thiazoline derivatives (sulfur analogues of known oxazolines) were prepared from chiral bis-(N-acylamino alcohols) with Lawesson's reagent. Bis-thiazolines thus obtained proved to be useful chiral ligands for metal in asymmetric Diels-Alder reaction.

引用

页码：1449 / 1450

页数：2

共 5 条

[1] Synthesis of new chiral thiazoline-containing ligands
Abrunhosa, I
Gulea, M
Levillain, J
Masson, S
[J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (20) : 2851 - 2859
[2] HELMCHEN G, 1991, SYNLETT, P257
[3] Nishio T, 2001, EUR J ORG CHEM, V2001, P3553
[4] Reaction of (1,omega)-N-acylamino alcohols with Lawesson's reagent: Synthesis of sulfur-containing heterocycles
Nishio, T
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (04) : 1106 - 1111
[5] Chiral heterocycles as ligands in asymmetric catalysis
Pfaltz, A
[J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1999, 36 (06) : 1437 - 1451

← 1 →