Effect of TiO2 Nano Fillers on the Electrical Conductivity of PSAN/TiO2 Polymer Nanocomposites

被引：3
|
作者：
Ningaraju, S. [1 ]
Munirathnamma, L. M. [1 ]
Kumar, K. V. Aneesh [1 ]
Ravikumar, H. B. [1 ]
机构：
[1] Univ Mysore, Dept Studies Phys, Mysore 570006, Karnataka, India
来源：
DAE SOLID STATE PHYSICS SYMPOSIUM 2015 | 2016年 / 1731卷
关键词：
free volume; nano-clusters; blocking effect; Space charge effect;
D O I：
10.1063/1.4947923
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
The microstructural characterization of Polystyrene co-acrylonitrile and Titanium dioxide (PSAN/TiO2) nanocomposites has been performed by Positron Annihilation Lifetime Spectroscopy. The decrease of positron lifetime parameters viz. o-Ps lifetime (tau(3)) and free volume size (V-f) up to 0.6 wt% of TiO2 is attributed to the filling of free volume holes by TiO2 nanoparticles. The increased free volume size (Vf) after 0.6 wt% of TiO2 indicates the formation of interface due to TiO2 nanoclusters. The variation of electrical conductivity at the lower and higher concentration of TiO2 in (PSAN/TiO2) nanocomposites is attributed to the blocking effect and space charge effect respectively.
引用
收藏
页数：3
相关论文
共 50 条
  • [1] Effect of TiO2 Nano-Filler on the Electrical Conductivity and Free Volume Parameters of PSAN/TiO2 Nanocomposites
    Ningaraju, S.
    Ravikumar, H. B.
    POLYMER COMPOSITES, 2018, 39 (05) : 1403 - 1412
  • [2] Effect of TiO2 Nanofiller on Electrical Conductivity of ABS/TiO2 Polymer Nanocomposites: A Free Volume Study
    Ningaraju, S.
    Munirathnamma, L. M.
    Aneeshkumar, K. V.
    Doreswamy, B. H.
    Ravikumar, H. B.
    MATERIALS TODAY-PROCEEDINGS, 2018, 5 (10) : 22454 - 22459
  • [3] Effect of cooling on electrical conductivity of TiO2
    Sheppard, L. R.
    Nowotny, M. K.
    Bak, T.
    Nowotny, J.
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2008, 245 (09): : 1816 - 1827
  • [4] Electrical properties of TiO2 nanocomposites
    Nelson, JK
    Hu, Y
    Thiticharoenpong, J
    2003 ANNUAL REPORT CONFERENCE ON ELECTRICAL INSULATION AND DIELECTRIC PHENOMENA, 2003, : 719 - 722
  • [5] The effect of nano-particle TiO2 fillers on structure and transport in polymer electrolytes
    Forsyth, M
    MacFarlane, DR
    Best, A
    Adebahr, J
    Jacobsson, P
    Hill, AJ
    SOLID STATE IONICS, 2002, 147 (3-4) : 203 - 211
  • [6] Electrical treeing breakdown characteristics of epoxy/TiO2 nanocomposites influenced by aggregates of nano-sized TiO2
    Murakami, Yoshinobu
    Yamada, Daichi
    Kodama, Norihiko
    Kawashima, Tomohiro
    Hozumi, Naohiro
    Yoshida, Shigeyoshi
    Umemoto, Takahiro
    Mabuchi, Takahiro
    Muto, Hirotaka
    IEEJ TRANSACTIONS ON ELECTRICAL AND ELECTRONIC ENGINEERING, 2022, 17 (03) : 486 - 492
  • [7] OXYGEN PARTIAL PRESSURE DEPENDENCE OF ELECTRICAL CONDUCTIVITY ON TiO2 AND Pd/TiO2
    Bratan, Veronica
    Hornoiu, Cristian
    Ionescu, Niculae I.
    REVUE ROUMAINE DE CHIMIE, 2012, 57 (4-5) : 513 - 519
  • [8] Effect of TiO2 morphology on in vitro bioactivity of polycaprolactone/TiO2 nanocomposites
    Tamjid, E.
    Bagheri, R.
    Vossoughi, M.
    Simchi, A.
    MATERIALS LETTERS, 2011, 65 (15-16) : 2530 - 2533
  • [9] Electrical properties of TiO2/SEO nanocomposites: From macro to nano
    Gutierrez, Junkal
    Tercjak, Agnieszka
    Martin, Loli
    Mondragon, Inaki
    ELECTROCHIMICA ACTA, 2011, 56 (16) : 5582 - 5586
  • [10] Effect of TiO2 on the Gas Sensing Features of TiO2/PANi Nanocomposites
    Duong Ngoc Huyen
    Nguyen Trong Tung
    Nguyen Duc Thien
    Le Hai Thanh
    SENSORS, 2011, 11 (02) : 1924 - 1931
12345