Polymerizable sol-gel precursor mediated synthesis of TiO2 supported zeolite-4A and its photodegradation of methylene blue

被引:61
作者
Nagarjuna, Ravikiran [1 ]
Roy, Sounak [1 ]
Ganesan, Ramakrishnan [1 ]
机构
[1] BITS Pilani, Dept Chem, Hyderabad 500078, Telangana, India
关键词
Polymerizable sol-gel; TiO2 supported zeolite; Photocatalysis; Methylene blue; TITANIUM-DIOXIDE NANOMATERIALS; PHOTOCATALYTIC DEGRADATION; ORGANIC-DYES; ZERO CHARGE; COMPOSITE; PERFORMANCE; NANOPARTICLES; ENVIRONMENT; ADSORPTION; OXIDATION;
D O I
10.1016/j.micromeso.2015.02.044
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A polymerizable sol-gel method has been employed to synthesize tailored TiO2 supported zeolite-4A. The synthetic procedure was optimized by using FTIR, TGA and DSC to prepare various TiO2 loading ranging from 10 to 30 wt% on the support The as-synthesized materials were characterized thoroughly with powder XRD, SEM, UV-Vis spectroscopy and BET surface area measurements. The characterization reveals that the polymerizable sal gel approach yields highly dispersed nano-crystalline TiO2 on the zeolite-4A support. The tailored materials exhibited high rate of photocatalytic degradation of methylene blue at alkaline pH. The used catalysts were subjected to recyclability investigations, which demonstrated highly stable surface of these materials. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码:1 / 8
页数:8
相关论文
共 59 条
[1]   Preparation, characterization and photocatalytic activity of TiO2 towards methylene blue degradation [J].
Arbuj, Sudhir S. ;
Hawaldar, Ranjit R. ;
Mulik, Uttamrao P. ;
Wani, Bina N. ;
Amalnerkar, Dinesh P. ;
Waghmode, Suresh B. .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2010, 168 (1-3) :90-94
[2]   Titanium Dioxide Nanomaterials for Sensor Applications [J].
Bai, Jing ;
Zhou, Baoxue .
CHEMICAL REVIEWS, 2014, 114 (19) :10131-10176
[3]   Graphene oxide-aluminium oxyhydroxide interaction and its application for the effective adsorption of fluoride [J].
Barathi, M. ;
Kumar, A. Santhana Krishna ;
Kumar, Chinta Uday ;
Rajesh, N. .
RSC ADVANCES, 2014, 4 (96) :53711-53721
[4]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[5]   Study on pH at the point of zero charge of TiO2 pH ion-sensitive field effect transistor made by the sputtering method [J].
Chou, JC ;
Liao, LP .
THIN SOLID FILMS, 2005, 476 (01) :157-161
[6]   Effect of TiO2 nanoparticles on the performance of polyphenylsulfone biomaterial for orthopaedic implants [J].
Diez-Pascual, Ana M. ;
Diez-Vicente, Angel L. .
JOURNAL OF MATERIALS CHEMISTRY B, 2014, 2 (43) :7502-7514
[7]   A Universal Scheme for Patterning of Oxides via Thermal Nanoimprint Lithography [J].
Dinachali, Saman Safari ;
Saifullah, Mohammad S. M. ;
Ganesan, Ramakrishnan ;
Thian, Eng San ;
He, Chaobin .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (17) :2201-2211
[8]   Nanoporous Sr-rich strontium titanate: a stable and superior photocatalyst for H2 evolution [J].
Feng, Liang-Liang ;
Zou, Xiaoxin ;
Zhao, Jun ;
Zhou, Li-Jing ;
Wang, De-Jun ;
Zhang, Xiao ;
Li, Guo-Dong .
CHEMICAL COMMUNICATIONS, 2013, 49 (84) :9788-9790
[9]   Tailoring elastic properties of PLGA/TiO2 biomaterials [J].
Fiedler, T. ;
Belova, I. V. ;
Murch, G. E. ;
Roether, J. A. ;
Boccaccini, A. R. .
COMPUTATIONAL MATERIALS SCIENCE, 2012, 61 :283-286
[10]   Photocatalytic decolorization of methylene blue in the presence of TiO2/ZnS nanocomposites [J].
Franco, A. ;
Neves, M. C. ;
Ribeiro Carrott, M. M. L. ;
Mendonca, M. H. ;
Pereira, M. I. ;
Monteiro, O. C. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 161 (01) :545-550