Solid state metathesis reaction for metal borides, silicides, pnictides and chalcogenides: Ionic or elemental pathways

被引：264
作者：
Parkin, IP
机构：
[1] Department of Chemistry, University College London, Christopher Ingold Laboratory, London WC1H 0AJ
来源：
CHEMICAL SOCIETY REVIEWS | 1996年 / 25卷 / 03期
关键词：
D O I：
10.1039/cs9962500199
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solid rate metathesis reactions offer a rapid, low external energy route to a range of inorganic ceramic materials including nitrides, oxides, pnictides, chalcogenides, silicides and borides. The reactions can be filament or bulk thermally initiated and often proceed with a thermal flash or propagation wave. The reactions can follow either an ionic metathetical or a reductive recombination pathway.
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页码：199 / +
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