Fully transparent and flexible humidity sensors fabricated by layer-by-layer self-assembly of thin film of poly(2-acrylamido-2-methylpropane sulfonate) and its salt complex

被引：46

作者：

Su, Pi-Guey ^{[1
]}

Li, Wei-Chen ^{[1
]}

Tseng, Jiun-Yi ^{[2
]}

Ho, Chao-Jen ^{[3
]}

机构：

[1] Chinese Culture Univ, Dept Chem, Taipei 111, Taiwan

[2] Acad Sinica, Inst Phys, Taipei, Taiwan

[3] Ind Technol Res Inst, Mat & Chem Res Labs, Hsinchu 310, Taiwan

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2011年 / 153卷 / 01期

关键词：

Transparent; Flexible; Humidity sensor; Aluminum-doped ZnO(AZO); Layer-by-layer (LBL) self-assembly; Polymer electrolyte; Salt; MULTILAYER FILMS; ACID; POLYELECTROLYTES; CONDUCTIVITY; CAPACITOR; NAFION;

D O I：

10.1016/j.snb.2010.09.074

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel fully transparent and flexible impedance-type humidity sensor was fabricated by the LBL self-assembly of poly(2-acrylamido-2-methylpropane sulfonate) (PAMPS) polymer electrolyte and PAMPS thin films that were doped with salts (NaCl and K2CO3) on a flexible substrate (polyester film; PET) substrate with a pair of comb-like aluminum-doped ZnO (AZO) transparent electrodes. The electrical properties of the LBL self-assembled PAMPS polymer electrolyte thin films were studied in detail as functions of relative humidity (RH), to elucidate the effects of the deposition concentration of PAMPS and the number of PAMPS multilayers on the sensing properties. NaCl and K2CO3 were simultaneously doped into PAMPS polyelectrolyte to improve the sensing properties (sensitivity and linearity) of the transparent and flexible impedance-type humidity sensors. The transparency, flexibility, hysteresis, ambient temperature, response and recovery times and long-term stability were also studied. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：29 / 36

页数：8

共 51 条

[1] Ion conductivity in poly(p-diethynylbenzene-co-propargyl alcohol) films doped with iron trichloride:: dependence on temperature
Camaioni, N
Casalbore-Miceli, G
Li, Y
Mari, CM
Yang, MJ
[J]. SOLID STATE IONICS, 2001, 144 (3-4) : 355 - 359
[2] Investigations on the ion transport mechanism in conducting polymer films
Casalbore-Miceli, G
Yang, MJ
Camaioni, N
Mari, CM
Li, Y
Sun, H
Ling, M
[J]. SOLID STATE IONICS, 2000, 131 (3-4) : 311 - 321
[3] Effect of the doping level on the conductance of polymer-salts complexes in the presence of humidity
Casalbore-Miceli, G
Yang, MJ
Li, Y
Camaioni, N
Martelli, A
Zanelli, A
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 2004, 97 (2-3): : 362 - 368
[4] Silicon carbide membrane relative humidity sensor with aluminium electrodes
Connolly, EJ
Pham, HTM
Groeneweg, J
Sarro, PM
French, PJ
[J]. MEMS 2004: 17TH IEEE INTERNATIONAL CONFERENCE ON MICRO ELECTRO MECHANICAL SYSTEMS, TECHNICAL DIGEST, 2004, : 193 - 196
[5] Thickness dependences of proton conductivity for ultrathin Nafion multilayers prepared via layer-by-layer assembly
Daiko, Yusuke
Katagiri, Kiyofumi
Yazawa, Tetsuo
Matsuda, Atsunori
[J]. SOLID STATE IONICS, 2010, 181 (3-4) : 197 - 200
[6] BUILDUP OF ULTRATHIN MULTILAYER FILMS BY A SELF-ASSEMBLY PROCESS .3. CONSECUTIVELY ALTERNATING ADSORPTION OF ANIONIC AND CATIONIC POLYELECTROLYTES ON CHARGED SURFACES
DECHER, G
HONG, JD
SCHMITT, J
[J]. THIN SOLID FILMS, 1992, 210 (1-2) : 831 - 835
[7] Fuzzy nanoassemblies: Toward layered polymeric multicomposites
Decher, G
[J]. SCIENCE, 1997, 277 (5330) : 1232 - 1237
[8] Polyelectrolyte membranes prepared by dynamic self-assembly of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA) for nanofiltration (I)
Deng, Hui-Yu
Xu, You-Yi
Zhu, Bao-Ku
Wei, Xiu-Zhen
Liu, Fu
Cui, Zhen-Yu
[J]. JOURNAL OF MEMBRANE SCIENCE, 2008, 323 (01) : 125 - 133
[9] Humidity sensing properties of nafion and sol-gel derived SiO2/Nafion composite thin films
Feng, CD
Sun, SL
Wang, H
Segre, CU
Stetter, JR
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 1997, 40 (2-3) : 217 - 222
[10] GOFF AHL, 1998, ELECTROCHIM ACTA, V44, P781

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