Bis[2,4-bis(2-pyridyl-κN)-6-(4-pyridyl)-1,3,5-triazine-κN3]ruthenium(II)bis(hexafluorophosphate)

被引：1

作者：

Hartshorn, RM ^{[1
]}

Zibaseresht, R ^{[1
]}

Robinson, WT ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805012420

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The coordination of Ru in the title compound, [ Ru( C18H12N6)(2)](PF6)(2), is octahedral. The coordination sphere is formed by six N atoms from the tridentate sites of two ligands that are meridionally oriented around the Ru-II ion. The locations of the donor atoms deviate substantially from an ideal octahedron. The Ru - N distances are in the range 1.983 ( 4) - 2.111 ( 4) &ANGS;. The Ru atom occupies a special position with twofold rotational symmetry. One of the P atoms occupies a special position with twofold rotational symmetry and the other P atom is located on a special position at a centre of symmetry.

引用

页码：M981 / M983

页数：3

共 23 条

[1] Red and blue luminescent metallo-supramolecular coordination polymers assembled through π-π interactions [J].

Alcock, NW ;

Barker, PR ;

Haider, JM ;

Hannon, MJ ;

Painting, CL ;

Pikramenou, Z ;

Plummer, EA ;

Rissanen, K ;

Saarenketo, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (09) :1447-1461

[2]

*BRUK AXS INC, 1999, SADABS SAINT PLUS VE

[3] Stepwise synthetic strategy for the preparation of trinuclear complexes of bis(terpyridyl) bridging ligands containing aza-crown macrocyclic spacer groups [J].

Bushell, KL ;

Couchman, SM ;

Jeffery, JC ;

Rees, LH ;

Ward, MD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (20) :3397-3403

[4] Synthesis, x-ray structure, and electrochemical and excited-state properties of multicomponent complexes made of a [Ru(Tpy)2]2+ unit covalently linked to a [2]-catenate moiety.: Controlling the energy-transfer direction by changing the catenate metal ion [J].

Cárdenas, DJ ;

Collin, JP ;

Gaviña, P ;

Sauvage, JP ;

De Cian, A ;

Fischer, J ;

Armaroli, N ;

Flamigni, L ;

Vicinelli, V ;

Balzani, V .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (23) :5481-5488

[5] A SINGLE STRANDED DIRUTHENIUM(II) HELICAL COMPLEX [J].

CATHEY, CJ ;

CONSTABLE, EC ;

HANNON, MJ ;

TOCHER, DA ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (08) :621-623

[6] A singly stranded, helical di-ruthenium(II) complex of a novel 6,6-ethynyl-linked bis(terpyridine) ligand. Distortion of the ethyne linkage and inversion of helicity [J].

Chamchoumis, CM ;

Potvin, PG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (09) :1373-1374

[7] THE COORDINATION CHEMISTRY OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE - THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE AND BIS(4'-PHENYL-2,2'-6',2''-TERPYRIDINE)NICKEL(II) CHLORIDE DECAHYDRATE [J].

CONSTABLE, EC ;

LEWIS, J ;

LIPTROT, MC ;

RAITHBY, PR .

INORGANICA CHIMICA ACTA, 1990, 178 (01) :47-54

[8] Dicobalt cluster functionalized 2,2′:6′,2"-terpyridine ligands and their ruthenium(II) complexes [J].

Constable, EC ;

Housecroft, CE ;

Johnston, LA ;

Armspach, D ;

Neuburger, M ;

Zehnder, M .

POLYHEDRON, 2001, 20 (06) :483-492

[9]

CONSTABLE EC, 1992, NEW J CHEM, V16, P855

[10] Structural studies of complexes of tridentate terimine systems.: Crystal structure of bis(2,2′:6′,2"-terpyridine)ruthenium(II) perchlorate hydrate, bis(2,2′:6′,2"-terpyridine)osmium(II) perchlorate hemihydrate and bis((1,10-phenanthrolin-2-yl)(pyridin-2-yl)amine)iron(II) tetrafluoroborate dihydrate [J].

Craig, DC ;

Scudder, ML ;

McHale, WA ;

Goodwin, HA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (12) :1131-1139

← 1 2 3 →