catena-Poly[[[(1,10-phenanthroline)copper(I)]-μ-cyanido] ethanol hemisolvate]

被引：3
作者：
Nie, Jianhua [1 ]
Wang, Jun [1 ]
Dai, Chuntao [1 ]
机构：
[1] Zhongshan Polytech, Zhongshan 528404, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
CRYSTAL-STRUCTURES; COPPER-CYANIDE;
D O I：
10.1107/S1600536810045186
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title coordination polymer, {[Cu(CN)(C(12)H(10)N(2))]center dot 0.5C(2)H(5)OH}(n), there are two Cu(I) ions, two 1,10-phenanthroline (phen) ligands and two cyanide ions in the asymmetric unit along with a highly disordered ethanol solvent molecule, which was modelled as being disordered over two sets of sites in a 0.829 (7):0.171 (7) ratio. The orientation/ordering of the C and N atoms of the cyanide ions could not be determined in the present refinement and they were modelled as being statistically disordered. Both copper ions are coordinated by an N,N'-bidentate phen ligand and two cyanide ligands, generating distorted tetrahedral CuN(2)Q(2) (Q = C or N) tetrahedra. The mu-cyanide ligands link the metal ions, forming a zigzag chain propagating in [001]. The chains are crosslinked by numerous aromatic pi-pi stacking contacts between adjacent phen rings [minimum centroid-centroid separation = 3.620 (3) angstrom].
引用
收藏
页码：M1538 / U560
页数：13
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