catena-Poly[[[(1,10-phenanthroline)copper(I)]-μ-cyanido] ethanol hemisolvate]

被引：3

作者：

Nie, Jianhua ^{[1
]}

Wang, Jun ^{[1
]}

Dai, Chuntao ^{[1
]}

机构：

[1] Zhongshan Polytech, Zhongshan 528404, Guangdong, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

CRYSTAL-STRUCTURES; COPPER-CYANIDE;

D O I：

10.1107/S1600536810045186

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title coordination polymer, {[Cu(CN)(C(12)H(10)N(2))]center dot 0.5C(2)H(5)OH}(n), there are two Cu(I) ions, two 1,10-phenanthroline (phen) ligands and two cyanide ions in the asymmetric unit along with a highly disordered ethanol solvent molecule, which was modelled as being disordered over two sets of sites in a 0.829 (7):0.171 (7) ratio. The orientation/ordering of the C and N atoms of the cyanide ions could not be determined in the present refinement and they were modelled as being statistically disordered. Both copper ions are coordinated by an N,N'-bidentate phen ligand and two cyanide ligands, generating distorted tetrahedral CuN(2)Q(2) (Q = C or N) tetrahedra. The mu-cyanide ligands link the metal ions, forming a zigzag chain propagating in [001]. The chains are crosslinked by numerous aromatic pi-pi stacking contacts between adjacent phen rings [minimum centroid-centroid separation = 3.620 (3) angstrom].

引用

页码：M1538 / U560

页数：13

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