A polymeric Mn complex with mixed pyridine-3,4-dicarboxylate/4,4′-bipyridine ligands:: [Mn2(C7H3NO4)2(C10H8N2)2]n•2nH2O

被引:25
作者
Zhang, QZ [1 ]
Lu, CZ [1 ]
Xia, CK [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
基金
中国国家自然科学基金;
关键词
manganese; pyridine-3,4-dicarboxylic acid; polymeric structure;
D O I
10.1016/j.inoche.2005.01.003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydrothermal reaction of Mn(CH3CO2)(2) . 4H(2)O, pyridine-3,4-dicarboxylic acid, 4,4'-bipyridine and H2O led to the formation of a polymeric Mn species, [Mn-2(C7H3NO4)(2)(C10H8N2)(2)](n) . 2nH(2)O. The complex presents a three-dimensional structure and exhibits intense fluorescent emission upon photo-excitation. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:304 / 306
页数:3
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