Electronically Mismatched Cycloaddition Reactions via First-Row Transition Metal, Iron(III)-Polypyridyl Complex

被引：37

作者：

Shin, Jung Ha ^{[1
]}

Seong, Eun Young ^{[1
]}

Mun, Hyeon Jin ^{[1
]}

Jang, Yu Jeong ^{[1
]}

Kang, Eun Joo ^{[1
]}

机构：

[1] Kyung Hee Univ, Dept Appl Chem, Yongin 17104, South Korea

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 18期

关键词：

VISIBLE-LIGHT PHOTOCATALYSIS; RADICAL-CATION; INTRAMOLECULAR CYCLOBUTANATION; STYRENE DERIVATIVES; DIMERIZATION; CATALYSIS; OXYGEN;

D O I：

10.1021/acs.orglett.8b02541

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The iron(III)-polypyridyl complex and its derivatives showed sufficient oxidizing potential to act as a one-electron oxidant, producing radical cations from olefins and promoting the efficient radical cation [2 + 2] and [2 + 4] cycloaddition reactions. Subsequent chain propagation afforded trisubstituted cyclobutane or cyclohexene derivatives, and this facile route enables the replacement of rare metals with sustainable, green, and inexpensive iron in radical cation cycloadditions.

引用

页码：5872 / 5876

页数：5

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