The catalytic effect of NiO on thermal decomposition of nitrocellulose

被引：34
作者：
Wei, Wenxian [1 ]
Cui, Bingbing [1 ]
Jiang, Xiaohong [1 ]
Lu, Ludu [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Peoples R China
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2010年 / 102卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Nitrocellulose; NiO; Thermal decomposition; Catalysis; AMMONIUM-PERCHLORATE; OXIDE;
D O I：
10.1007/s10973-010-0695-y
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The catalytic effect of NiO on thermal decomposition of nitrocellulose (NC) has been investigated via thermogravimetry-mass spectrometry (TG-MS) coupling technique, and the residue of NC with 20% NiO reacted in tubular furnace was analyzed by X-ray diffraction (XRD). TG-MS analysis showed that adding 2% NiO to NC accelerated the thermal decomposition process and promoted the generation of gaseous products. The catalytic mechanism was based on the accelerated generation of NO2, which further reacted with the radical to produce other gaseous products. XRD analysis of catalyst residue showed that Ni was formed during the catalytic reaction.
引用
收藏
页码：863 / 866
页数：4
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