Pressure-induced switching in a copper(II) citrate dimer

被引：29

作者：

Galloway, Kyle W. ^{[3
]}

Moggach, Stephen A. ^{[1
,2
]}

Parois, Pascal ^{[3
]}

Lennie, Alistair R. ^{[4
]}

Warren, John E. ^{[4
]}

Brechin, Euan K. ^{[1
,2
]}

Peacock, Robert D. ^{[3
]}

Valiente, Rafael ^{[5
]}

Gonzalez, Jesus ^{[6
]}

Rodriguez, Fernando ^{[6
]}

Parsons, Simon ^{[1
,2
]}

Murrie, Mark ^{[3
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Edinburgh, Ctr Sci Extreme Condit, Edinburgh EH9 3JJ, Midlothian, Scotland

[3] Univ Glasgow, WestCHEM, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

[4] STFC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

[5] Univ Cantabria, Fac Ciencias, Dpt Fis Aplicada, MALTA Consolider Team, E-39005 Santander, Spain

[6] Univ Cantabria, Fac Ciencias, DCITIMAC, MALTA Consolider Team, E-39005 Santander, Spain

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

LUMINESCENCE; TRANSITION; COMPLEXES; SPECTRA; ANVIL; MN;

D O I：

10.1039/c001376e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High pressure single crystal X-ray diffraction and high pressure single crystal electronic spectroscopic studies of a copper(II) citrate dimer are reported, allowing us to correlate the change in local structure at the Cu(II) centres with the observed piezochromism.

引用

页码：2516 / 2519

页数：4

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