Electron-rich and electron-poor heterobimetallic butterfly clusters:: synthesis and structure of [Ru3Ir(CO)8(μ3-H)(μ-Cl)2(μ-PtBu2)2(tBu2PH)] and [Ru3Au(CO)10(μ-Cl)(tBu2PH)]

被引：11

作者：

Böttcher, HC ^{[1
]}

Graf, M ^{[1
]}

Merzweiler, K ^{[1
]}

Wagner, C ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Dept Chem, D-06120 Halle, Germany

来源：

POLYHEDRON | 2000年 / 19卷 / 26-27期

关键词：

ruthenium; iridium; gold; electron-rich; cluster; phosphido-bridged; crystal structures;

D O I：

10.1016/S0277-5387(00)00561-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster [Ru3Ir(CO)(8)(mu (3)-H)(mu -Cl)(2)(mu -(PBu2)-Bu-t)(2)((Bu2PH)-Bu-t)] (3) has been isolated from the reaction of [Ru-3(CO)(12)] with [Ir((Bu2PH)-Bu-t)(3)Cl] in refluxing toluene. The analogous reaction of [Ru-3(CO)(12)] with [Au((Bu2PH)-Bu-t)Cl] in refluxing THF gave [Ru3Au(CO)(10)(mu -Cl)((Bu2PH)-Bu-t)] (4) in good yield. The single-crystal X-ray structure analyses reveal both clusters to contain a Ru3M butterfly skeleton. With respect to the EAN electron count of 62e, 3 can be considered as electron-rich (64e), while 4 is electron-poor (60e). (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：2593 / 2598

页数：6

共 13 条

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