Hydrogen storage for off-grid power supply

被引:124
作者
Gray, E. MacA [1 ]
Webb, C. J. [1 ]
Andrews, J. [2 ]
Shabani, B. [2 ]
Tsai, P. J. [3 ]
Chan, S. L. I. [3 ]
机构
[1] Griffith Univ, Queensland Micro & Nanotechnol Ctr, Nathan, Qld 4111, Australia
[2] RMIT Univ, Sch Aerosp Mech & Mfg Engn, Melbourne, Vic 3083, Australia
[3] Univ New S Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
关键词
Remote-area power supply; Electrolyser; Hydrogen storage; Fuel cell; PEM FUEL-CELL; ABSORPTION; PERFORMANCE; INTEGRATION; HYSTERESIS; STABILITY; LANI5-H;
D O I
10.1016/j.ijhydene.2010.09.051
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The use of intermittent renewable energy sources for power supply to off-grid electricity consumers depends on energy storage technology to guarantee continuous supply. Potential applications of storage-guaranteed systems range from small installations for remote telecoms, water-pumping and single dwellings, to farms and whole communities for whom grid connection is too expensive or otherwise infeasible, to industrial, military and humanitarian uses. In this paper we explore some of the technical issues surrounding the use of hydrogen storage, in conjunction with a PEM electrolyser and PEM fuel cell, to guarantee electricity supply when the energy source is intermittent, most typically solar photovoltaic. We advocate metal-hydride storage and compare its energy density to that of Li-ion battery storage, concluding that a significantly smaller package is possible with metal-hydride storage. A simple approach to match the output of a photovoltaic array to an electrolyser is presented. The properties required for the metal-hydride storage material to interface the electrolyser to the fuel cell are discussed in detail. It is concluded that relatively conventional Mischmetal-based AB(5) alloys are suitable for this application. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:654 / 663
页数:10
相关论文
共 34 条
[1]  
ALI S, 2006, 16 WORLD HYDR EN C L
[2]   Characterisation of a 3 kW PEFC power system coupled with a metal hydride H2 storage [J].
Bossi, C. ;
Del Corno, A. ;
Scagliotti, M. ;
Valli, C. .
JOURNAL OF POWER SOURCES, 2007, 171 (01) :122-129
[3]  
CHAO BS, 2004, P MAT RES SOC S, V801
[4]   Study of the performance of Ti-Zr based hydrogen storage alloys [J].
Chuang, HJ ;
Chan, SLI .
JOURNAL OF POWER SOURCES, 1999, 77 (02) :159-163
[5]   Effect of Ni encapsulation on the properties of Ti-Zr-based hydrogen storage alloys [J].
Chuang, HJ ;
Chan, SLI .
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 314 (1-2) :224-231
[6]   Direct coupling of an electrolyser to a solar PV system for generating hydrogen [J].
Clarke, R. E. ;
Giddey, S. ;
Ciacchi, F. T. ;
Badwal, S. P. S. ;
Paul, B. ;
Andrews, J. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (06) :2531-2542
[7]   STATIC, DYNAMIC AND CYCLING STUDIES ON HYDROGEN IN THE INTERMETALLICS LANI5 AND LANI4.77AL0.22 [J].
DANTZER, P .
JOURNAL OF THE LESS-COMMON METALS, 1987, 131 :349-363
[8]   HYSTERESIS EFFECTS IN CERIUM-CONTAINING LANI5-TYPE COMPOUNDS [J].
DAYAN, D ;
MINTZ, MH ;
DARIEL, MP .
JOURNAL OF THE LESS-COMMON METALS, 1980, 73 (01) :15-24
[9]   Theory, modelling and performance measurement of unitised regenerative fuel cells [J].
Doddathimmaiah, A. ;
Andrews, J. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (19) :8157-8170
[10]  
*ECD OV, ECD OV SAL BROCH