Glycosyl trifluoroacetimidates. Part 1: Preparation and application as new glycosyl donors

被引：354
作者：
Yu, B [1 ]
Tao, HC [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 12期
基金：
中国国家自然科学基金;
关键词：
glycosyl trifluoroacetimidate; glycosylation; glycosyl donor;
D O I：
10.1016/S0040-4039(01)00157-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Glycosyl (N-phenyl)trifluoroacetimidates, readily prepared from 1-hydroxyl sugars by treatment with (N-phenyl)trifluoroacetimidoyl chloride in the presence of K2CO3, were demonstrated to be effective glycosyl donors. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2405 / 2407
页数：3
相关论文
共 14 条
  • [1] Recent developments in chemical oligosaccharide synthesis
    Boons, GJ
    [J]. CONTEMPORARY ORGANIC SYNTHESIS, 1996, 3 (03): : 173 - 200
  • [2] Recent developments in oligosaccharide synthesis
    Davis, BG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (14): : 2137 - 2160
  • [3] Synthesis of three diosgenyl saponins: dioscin, polyphyllin D, and balanitin 7
    Deng, SJ
    Yu, B
    Hui, YZ
    Yu, H
    Han, XW
    [J]. CARBOHYDRATE RESEARCH, 1999, 317 (1-4) : 53 - 62
  • [4] A facile synthetic approach to a group of structurally typical diosgenyl saponins
    Deng, SJ
    Yu, B
    Hui, YZ
    [J]. TETRAHEDRON LETTERS, 1998, 39 (36) : 6511 - 6514
  • [5] Larson DP, 1997, J ORG CHEM, V62, P8406, DOI 10.1021/jo971413u
  • [6] Total synthesis of tricolorin A
    Lu, SF
    Oyang, QQ
    Guo, ZW
    Yu, B
    Hui, YZ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (24) : 8400 - 8405
  • [7] NOVEL SYNTHESIS OF 1,2-CIS-DISACCHARIDES
    POUGNY, JR
    JACQUINET, JC
    NASSR, M
    DUCHET, D
    MILAT, ML
    SINAY, P
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) : 6762 - 6763
  • [8] POUGNY JR, 1976, TETRAHEDRON LETT, P4073
  • [9] FACILE SYNTHESIS OF ALPHA-O-GLYCOSYL AND BETA-O-GLYCOSYL IMIDATES - PREPARATION OF GLYCOSIDES AND DISACCHARIDES
    SCHMIDT, RR
    MICHEL, J
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (09): : 731 - 732
  • [10] NEW METHODS FOR THE SYNTHESIS OF GLYCOSIDES AND OLIGOSACCHARIDES - ARE THERE ALTERNATIVES TO THE KOENIGS-KNORR METHOD
    SCHMIDT, RR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (03): : 212 - 235
12