Crystal structure of mono[3-(2-imidazolylthio)]-altro-β-cyclodextrin:: elliptical distortion of the cavity and unique 'Yin-Yang' stacking

被引：21

作者：

Lindner, HJ

Yuan, DQ

Fujita, K

Kubo, K

Lichtenthaler, FW

机构：

[1] Nagasaki Univ, Grad Sch Biomed Sci, Dept Mol Med Sci, Nagasaki 8528521, Japan

[2] TH Darmstadt, Inst Organ Chem, D-64287 Darmstadt, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b303788f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound is elliptically distorted due to the unusual C-1(4) geometry of the altrose portion. In packing, a unique fourfold helical structure is elaborated with head-to-head dimers as the repeating motif. The imidazolyl moieties mutually reside on each other's cavities thereby resembling the Yin-Yang type balancing of antagonisms.

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页码：1730 / 1731

页数：2

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