Two new hybrid compounds assembled from Keggin-type polyoxometalates and transition metal coordination complexes

被引：18

作者：

Wang, Yan ^{[1
,2
]}

Zou, Bo ^{[2
]}

Xiao, Li-Na ^{[1
,2
]}

Jin, Ning ^{[3
]}

Peng, Yu ^{[1
,2
]}

Wu, Feng-Qing ^{[2
]}

Ding, Hong ^{[1
,2
]}

Wang, Tie-Gang ^{[1
,2
]}

Gao, Zhong-Min ^{[1
,2
]}

Zheng, Da-Fang ^{[1
,2
]}

Cui, Xiao-Bing ^{[1
,2
]}

Xu, Ji-Qing ^{[1
,2
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[3] Jilin Univ, China Japan Union Hosp, Changchun 130023, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2011年 / 184卷 / 03期

关键词：

Polyoxometalate; Hydrothermal synthesis; Pseudo-Keggin; Hydrogen bonds; HYDROTHERMAL SYNTHESIS; STRUCTURAL-CHARACTERIZATION; 2-DIMENSIONAL FRAMEWORK; CRYSTAL-STRUCTURE; CLUSTERS; ARCHITECTURES; POLYMER; 1D; OCTAMOLYBDATE; SOLIDS;

D O I：

10.1016/j.jssc.2011.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new hybrid compounds based on Keggin-type polyoxometalates: {[PMo12O40][Ni(Phen)(2) (H2O)](2))center dot K center dot 2OH(-) (1) and [Cd-2(Phen)(4)Cl-2][HPW12O40]center dot H2O (2) (Phen=1,10-phenanthroline), have been prepared and characterized by IR, UV-vis, XPS, XRD and single crystal X-ray diffraction analyses. Compound 1 exhibits a 1-D chain structure constructed from Pseudo-Keggin polyoxometalate bi-supported transition metal coordination complexes linked by K+ ions. Compound 2 contains Pseudo-Keggin polyoxoanions [HPW12O40](2-) and novel metal-chloride-ligand coordination complexes [Cd-2(Phen)(4)Cl-2](2+). (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：557 / 562

页数：6

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