Unexpected C-Se Cross-Coupling Reaction: Copper Oxide Catalyzed Synthesis of Symmetrical Diaryl Selenides via Cascade Reaction of Selenourea with Aryl Halides/Boronic Acids

被引：48

作者：

Reddy, V. Prakash ^{[1
]}

Kumar, A. Vijay ^{[1
]}

Rao, K. Rama ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 24期

关键词：

STEREOSELECTIVE-SYNTHESIS; GLUTATHIONE-PEROXIDASE; UNSYMMETRICAL DIARYL; ORGANOSELENIUM COMPOUNDS; DIORGANO DISELENIDES; VINYL SELENIDES; HALIDES; IODIDE; CHEMISTRY; ARYLATION;

D O I：

10.1021/jo102017g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selenourea is used as an effective selenium surrogate in the C Se cross-coupling reaction catalyzed by copper oxide nanoparticles under ligand free conditions. This protocol has been utilized for the synthesis of a variety of symmetrical diaryl selenides in good to excellent yields from the readily available aryl halides/boronic acids.

引用

页码：8720 / 8723

页数：4

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