Selective C(sp3)-H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2 as a sustainable oxidant

被引：51

作者：

Zhang, Yongqiang ^{[1
]}

Jin, Yunhe ^{[1
]}

Wang, Lifang ^{[1
]}

Zhang, Qingqing ^{[1
]}

Meng, Changgong ^{[1
]}

Duan, Chunying ^{[1
]}

机构：

[1] Dalian Univ Technol, Zhang Dayu Sch Chem, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

GREEN CHEMISTRY | 2021年 / 23卷 / 18期

基金：

中国国家自然科学基金;

关键词：

OXIDATIVE CYCLIZATION; 2-ISOCYANOBIPHENYLS; ALKALOIDS; FUNCTIONALIZATIONS; PHOTOSENSITIZER; PHOTOCATALYSIS; DERIVATIVES; CHEMISTRY;

D O I：

10.1039/d1gc02670d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The visible light-induced metal-free C(sp(3))-H phenanthridinylation of simple alkanes with isonitrile is developed with H2O2 as a terminal green oxidant. This reaction features good yields and selectivities, mild conditions, and a broad substrate scope with gaseous alkanes involved, allowing practical access to valuable alkyl-substituted phenanthridine derivatives.

引用

收藏

页码：6926 / 6930

页数：5

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