Critical factors influencing the structures and properties of metal-organic frameworks

被引：40

作者：

Shen, Kang ^{[1
]}

Zhang, Mingdao ^{[1
]}

Zheng, Hegen ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Adv Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 05期

基金：

中国国家自然科学基金;

关键词：

SECONDARY BUILDING UNITS; COORDINATION POLYMERS; SUPRAMOLECULAR ISOMERISM; HYDROTHERMAL SYNTHESIS; POLYCARBOXYLATE ACIDS; CRYSTAL-STRUCTURES; LIGAND; CLUSTER; DESIGN; 2D;

D O I：

10.1039/c4ce02150a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) have emerged as an important family of compounds that have fascinating structures and diverse applications. But until now, targeted synthesis of MOFs with desired frameworks is still a challenge. In order to appreciate the properties and to design new frameworks, it is necessary to understand how to rationalize the design and synthesis of MOFs from a fundamental perspective. This highlight review will outline the recent advances in this topic from both our and other groups and provide an overview of the different factors influencing the structures of MOFs. These examples illustrate some of the present trends concerning the design of organic ligands and SBUs, coordination assemblies, and experimental conditions.

引用

页码：981 / 991

页数：11

共 64 条

[1] Supramolecular isomerism in coordination compounds: Nanoscale molecular hexagons and chains [J].