Transition-metal-catalyzed remote C-H functionalization of thioethers

被引:18
作者
Feng, Xiao-Qing [1 ,2 ]
Wang, He-Cheng [1 ,2 ]
Li, Zhi [3 ]
Tang, Long [1 ,2 ]
Sun, Xiaoqiang [3 ]
Yang, Ke [3 ]
机构
[1] Changzhou Univ, Sch Pharm, Changzhou 213164, Jiangsu, Peoples R China
[2] Changzhou Univ, Sch Med, Changzhou 213164, Jiangsu, Peoples R China
[3] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China
关键词
TRANSIENT DIRECTING GROUPS; BOND FORMATION; SULFUR; BORYLATION; ACTIVATION; ALKENYLATION; LIGAND; ARYLATION; CLEAVAGE; ANALOGS;
D O I
10.1039/d2ra01268e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the last decade, transition-metal-catalyzed direct C-H bond functionalization has been recognized as one of most efficient approaches for the derivatization of thioethers. Within this category, both mono- and bidentate-directing group strategies achieved the remote C(sp(2))-H and C(sp(3))-H functionalization of thioethers, respectively. This review systematically introduces the major advances and their mechanisms in the field of transition-metal-catalyzed remote C-H functionalization of thioethers from 2010 to 2021.
引用
收藏
页码:10835 / 10845
页数:11
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