Performance of Metal-Supported Composite and Single-Phase Cathodes Based on LSCF and SSC

被引:8
作者
Harris, J. [1 ]
Kesler, O. [1 ,2 ]
机构
[1] Univ Toronto, Dept Mech & Ind Engn, Toronto, ON M5S 3G8, Canada
[2] Univ Toronto, Ctr Sustainable Energy, Toronto, ON M5S 3G8, Canada
来源
SOLID OXIDE FUEL CELLS 12 (SOFC XII) | 2011年 / 35卷 / 01期
基金
加拿大自然科学与工程研究理事会;
关键词
OXIDE FUEL-CELLS; SOFC;
D O I
10.1149/1.3570182
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Cathodes based on La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) and Sm0.5Sr0.5CoO3-delta (SSC) were fabricated by axial-injection plasma spraying using dry powder feedstock. Composite cathodes were produced with up to 40 wt.% Ce0.80Sm0.20O2-delta (SDC) in the feedstock. The processing parameters were varied to produce cathodes with different mechanical properties and microstructures. The best-performing LSCF-SDC cathode had a polarization resistance (Rp) of 0.101 Omega cm(2) at 750 degrees C, and the best-performing SSC cathode had a polarization resistance of 0.0056 Omega cm(2).
引用
收藏
页码:1927 / 1934
页数:8
相关论文
共 21 条
[1]   Improving Stoichiometry and Processing of LSCF Oxygen Electrode for SOFC [J].
Ansar, A. ;
Soysal, D. ;
Ilhan, Z. ;
Wagner, N. ;
Wolf, S. ;
Ruckdaeschel, R. .
SOLID OXIDE FUEL CELLS 11 (SOFC-XI), 2009, 25 (02) :2443-2453
[2]  
Ansar A., 2010, THERM SPRAY 2008 P I, P123
[3]   Electrochemical characteristics of LSCF-SDC composite cathode for intermediate temperature SOFC [J].
Fu, Changjing ;
Sun, Kening ;
Zhang, Naiqing ;
Chen, Xinbing ;
Zhou, Derui .
ELECTROCHIMICA ACTA, 2007, 52 (13) :4589-4594
[4]   Fabrication of Composite LSCF-SDC Cathode Coatings By Plasma Spray Processing [J].
Harris, J. ;
Kesler, O. .
SOLID OXIDE FUEL CELLS 11 (SOFC-XI), 2009, 25 (02) :2455-2461
[5]   Atmospheric Plasma Spraying Low-Temperature Cathode Materials for Solid Oxide Fuel Cells [J].
Harris, J. ;
Kesler, O. .
JOURNAL OF THERMAL SPRAY TECHNOLOGY, 2010, 19 (1-2) :328-335
[6]  
Harris J., 2011, INT THERM SPRA UNPUB
[7]   High performance metal-supported intermediate temperature solid oxide fuel cells fabricated by atmospheric plasma spraying [J].
Hwang, Chang-sing ;
Tsai, Chun-Huang ;
Yu, Jen-Feng ;
Chang, Chun-Liang ;
Lin, Jun-Meng ;
Shiu, Yaw-Hwa ;
Cheng, Shih-Wei .
JOURNAL OF POWER SOURCES, 2011, 196 (04) :1932-1939
[8]  
LAGERBOM J, 2008, THERM SPRAY 2008 P I, P1103
[9]  
Murray EP, 2002, SOLID STATE IONICS, V148, P27, DOI 10.1016/S0167-2738(02)00102-9
[10]   High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC) [J].
Schiller, G. ;
Ansar, A. ;
Lang, M. ;
Patz, O. .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2009, 39 (02) :293-301