Structural differential scanning calorimetric and spectroscopic studies of the new two-dimensional compound (C4H9NH3)(2)SnCl6

被引：8
|
作者：
Elleuch, H
Kamoun, M
Daoud, A
Jouini, T
机构：
[1] ECOLE NATL INGN SFAX,LAB ETAT SOLIDE,SFAX,TUNISIA
[2] FAC SCI,LAB CHIM MINERALE,TUNIS,TUNISIA
来源：
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH | 1996年 / 157卷 / 01期
关键词：
D O I：
10.1002/pssa.2211570102
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The structure of (C4H9NH3)(2)SnCl6 is orthorhombic, M(m) = 479.68, Pnma, a = 12.242(3)Angstrom, b = 7.329(3)Angstrom, c = 21.527(4)Angstrom, Z = 4, V = 1931.4(11)Angstrom(3), D = 1650 mg/m(3), lambda = 0.71069 Angstrom, T = 293(2) K, R = 0.044 for 1900 reflections with I > 2 sigma(I). The structure is characterized by ionic layers sandwiched between layers of paraffinic chains. A structural phase transition is detected by means of differential scanning calorimetry. The basic thermodynamic data are determined for this transition. The Raman and infrared spectra at room temperature are recorded and some frequencies are assigned.
引用
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页码：3 / 9
页数：7
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