Dibromo[(Z)-2-bromo-2-(hydroxymethyl)-vinyl](n-butyl)tellurium(IV)

被引：8

作者：

Zukerman-Schpector, J

Stefani, HA

Silva, DD

Braga, AL

Dornelles, L

Silveira, CD

Caracelli, I

机构：

[1] Univ Fed Sao Carlos, Dept Quim, Lab Cristalog Estereodinam & Modelagem Mol, BR-13565 Sao Carlos, SP, Brazil

[2] USP, Inst Quim, Sao Paulo, Brazil

[3] USP, Fac Ciencias Farmaceut, BR-09500900 Sao Paulo, Brazil

[4] Univ Fed Santa Maria, Dept Quim, Santa Maria, RS, Brazil

[5] Univ Fed Sao Carlos, Dept Fis, BR-13560 Sao Carlos, SP, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198009573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, [TeBr2(C4H9)(C3H4BrO)] Or C7H13Br3OTe, the primary geometry about the Te-IV atom is a pseudo-trigonal-bipyramidal arrangement with axial bromines and one equatorial position vacant. If an intermolecular secondary Te ... O bond of 3.041 (5) Angstrom, trans to the Te-C(vinylic) bond, is taken into consideration, the structure may be regarded as pseudo-octahedral. Distances and angles are: Te-Br 2.7295 (10) and 2.6115 (10), Te-C 2.092 (6) and 2.134 (7) Angstrom, Br-Te-Br 176.59 (3), Br-Te-C 88.87 (19), 89.0 (3), 89.65 (19) and 88.2 (3), and C-Te-C 99.7 (3)degrees. The lattice is formed by hydrogen-bonded centrosymmetric dimers [O ... Br = 3.399 (6) Angstrom], which, in turn, are linked by the intermolecular secondary Te ... O bond.

引用

页码：2007 / 2009

页数：3

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