Rovibrational energy transfer in the He-C3 collision: rigid bender treatment of the bending-rotation interaction and rate coefficients

被引:25
作者
Stoecklin, Thierry [1 ]
Denis-Alpizar, Otoniel [1 ]
Halvick, Philippe [1 ]
机构
[1] Univ Bordeaux, CNRS UMR 5255, Inst Sci Mol, F-33405 Talence, France
关键词
astrochemistry; molecular data; molecular processes; scattering; ISM: kinematics and dynamics; ISM: molecules; TRANSLUCENT CLOUD; INTERSTELLAR C-3; TRANSITIONS; EXCITATION;
D O I
10.1093/mnras/stv491
中图分类号
P1 [天文学];
学科分类号
0704 ;
摘要
C-3 is a molecular chain which has been observed in interstellar clouds and in comets. It is also a very floppy molecule for which the vibrational bending transitions are in the same energy range as the rotational transitions. In this paper, we apply our recently developed quantum scattering method for treating atom rigid bender inelastic collisions at the Close Coupling level to the collision of C-3 by helium. This method allows us to compute the rovibrational transitions induced by collisions. The purely rotational transitions have been also calculated, using the rigid monomer approximation. The accuracy of this last approximation in the case of a system with a significant vibrational-rotational coupling is discussed. The first evaluation of the cross-sections associated with the rovibrational transitions between levels belonging to different vibrational bending levels is also presented. We observe that the propensity rule for the rovibrational transitions is a competition between the smallest Delta j and the smallest transition energy. As a consequence, cross-sections and rate coefficients of vibrationally inelastic transitions can be several orders of magnitude larger than for purely rotational transitions.
引用
收藏
页码:3420 / 3425
页数:6
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