Charge-Transfer Adducts of Chalcogenourea Derivatives of N-Heterocyclic Carbenes with Iodine Monochloride

被引：2

作者：

Saab, Marina ^{[1
]}

Nahra, Fady ^{[2
,3
]}

Van Hecke, Kristof ^{[1
]}

机构：

[1] Univ Ghent, Dept Chem, XStruct, Krijgslaan 281,Bldg S3, B-9000 Ghent, Belgium

[2] Univ Ghent, Dept Chem, Krijgslaan 281,Bldg S3, B-9000 Ghent, Belgium

[3] VITO Flemish Inst Technol Res, Boeretang 200, B-2400 Mol, Belgium

来源：

MOLBANK | 2022年 / 2022卷 / 01期

关键词：

selenourea; thiourea; N-heterocyclic carbene; iodine monochloride; RAY CRYSTAL-STRUCTURES; STRUCTURAL-CHARACTERIZATION; MOLECULAR ADDUCTS; DIIODINE ADDUCTS; COMPLEXES; MECHANISM; DONORS; SE; BENZIMIDAZOLE-2-THIONE; THIOAMIDES;

D O I：

10.3390/M1344

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this communication, we investigate the reaction between seleno- and thiourea, derived from N-heterocyclic carbenes, with the interhalogen iodine monochloride. The formation of all three products was confirmed by NMR spectroscopy, while single-crystal X-ray analyses were able to establish a charge-transfer coordination type, which showed a linear Se/S-I-Cl arrangement, for all adducts formed. Based on a detailed crystallographic analysis, we can deduce the zwitterionic character of these compounds.

引用

页数：8

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