Solubility of 1,3,3-Trinitroazetidine in Ethanol plus Water Systems from (293.15 K to 323.15 K)

被引:12
作者
Zhang, Jing [1 ]
Hu, Jin-Wei [1 ]
Wang, Jian-Long [1 ]
Chen, Li-Zhen [1 ]
机构
[1] N Univ China, Sch Chem Engn & Environm, Taiyuan 030051, Peoples R China
关键词
TNAZ; Solubility; Liquid-solid equilibrium; Laser monitoring observation technique; Correlation; MIXED-SOLVENT SYSTEMS; MATHEMATICAL REPRESENTATION; THERMODYNAMIC PROPERTIES; MODEL; NIBS;
D O I
10.1007/s10953-011-9673-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solubilities of 1,3,3-trinitroazetidine, TNAZ, in pure solvent and mixed solvents were measured using a synthetic method. The laser monitoring technique was used to determine the disappearance of the solid phase in a solid + liquid mixture. All data were measured at atmospheric pressure and temperatures ranging from (293.15 to 323.15) K. The effect of solvent composition and temperature on the solubility was discussed. The experimental data were correlated with an empirical equation.
引用
收藏
页码:703 / 708
页数:6
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