Tributylammonium chlorochromate, (C4H9)3NH[CrO3Cl] (TriBACC):: A new, mild and stable oxidant for organic substrates

被引：13

作者：

Ghammamy, S ^{[1
]}

Mazareey, M ^{[1
]}

机构：

[1] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin, Iran

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2005年 / 70卷 / 05期

关键词：

oxidant; chromium(VI) reagent; tributylammonium chlorochromate; oxidation; organic substrates;

D O I：

10.2298/JSC0505687G

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild and stable new chromium(VI) reagent from tributylamine is described. Orange crystalline tributylammonium chlorochromate(VI), (C4H9)(3)NE[CrO3Cl], (TriBACC), is easily prepared in a nearly quantitative yield by the interaction of tributylamine with CrO3 and hydrochloric acid in a 1:2:2 mole ratio. This reagent is a versatile reagent for the effective and selective oxidation of organic substratcs, in particular for alcohols, under mild conditions.

引用

页码：687 / 693

页数：7

共 5 条

[1] Synthesis and Characterization of a New Oxidation Reagent: Tetrahexylammonium Chlorochromate, (C6H13)4N[CrO3Cl]
Koohestani, Behnam
Javanshir, Zahra
Ghammamy, Shahriare
Mehrani, Kheyrollah
Afrand, Hamid
Saghatforoush, Lotfali
JOURNAL OF THE MEXICAN CHEMICAL SOCIETY, 2008, 52 (02) : 116 - 119
[2] Oxidation of organic substrates using two triethylammonium halochromates(VI), (C2H5)3NH[CrO3X], (X=F, Cl) supported on silica gel
Ghammamy, Shahriare
Dastpeyman, Samaneh
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2008, 55 (01) : 229 - 232
[3] Methyltriphenylphosphonium Halochromates, [Me(Ph)(3)P][CrO3X] (MTriPPXC) (X= F, Cl, Br): the Three New, Mild and Stable Oxidants for Organic Substrates
Ghammamy, Shahriare
Mehrani, Kheyrollah
Maleki, Saeid
Javanshir, Zahra
GAZI UNIVERSITY JOURNAL OF SCIENCE, 2008, 21 (02): : 33 - 36
[4] Oxidation of Some Organic Diols with Trialkylammonium Fluorochromates(VI), R3NH[CrO3F], (R= CH3, C2H5, C3H7 and C4H9) at Room Temperature and Under Microwave Condition
Ghammamy, Shahriar
Khorsandtabar, Samira
Moghimi, Ali
Sahebalzamani, Hajar
JOURNAL OF THE MEXICAN CHEMICAL SOCIETY, 2009, 53 (02) : 41 - 43
[5] Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation
Sendil, Kivilcim
Ozgun, H. Beytiye
Ustun, Ebru
JOURNAL OF CHEMISTRY, 2016, 2016

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