Synthesis, crystallization and tensile properties of poly(ethylene terephthalate-co-2,6-naphthalate)s with low naphthalate units content

被引：14
作者：
Karayannidis, GP [1 ]
Papachristos, N [1 ]
Bikiaris, DN [1 ]
Papageorgiou, GZ [1 ]
机构：
[1] Aristotle Univ Thessaloniki, Dept Chem, Lab Organ Chem Technol, GR-54124 Thessaloniki, Macedonia, Greece
来源：
POLYMER | 2003年 / 44卷 / 26期
关键词：
poly(ethylene naphthalate); copolymer; mechanical properties;
D O I：
10.1016/j.polymer.2003.10.037
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of poly(ethylene terephthalate-co-naphthalate)s (PETN copolymers) with low naphthalate units content was synthesized. A melting point depression was observed, while the glass transition temperatures were slightly higher than that of Polyethylene terephthalate (PET). Crystallization rates of the copolymers decreased with increasing comonomer content. WAXD patterns showed that only PET crystals were formed. Co-crystallization behaviour was evaluated on the basis of the Wendling-Suter model. The tensile properties of the copolymers PETN 97/3 and PETN 94/6, Young's modulus yield stress and elongation at break was significantly improved compared to PET. WAXD showed that some crystalline precursor was generated during drawing of the specimens. DSC traces of the drawn specimens showed enhanced crystallization rates compared to that of the original amorphous specimens. (C) 2003 Published by Elsevier Ltd.
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收藏
页码：7801 / 7808
页数：8
相关论文
共 40 条
  • [1] Allegra G., 1969, ADV POLYM SCI, V6, P549
  • [2] [Anonymous], [No title captured]
  • [3] BAUR H, 1966, MAKROMOLEKUL CHEM, V98, P297
  • [4] Bicerano J, 1998, J MACROMOL SCI R M C, VC38, P391
  • [5] Brandrup J, 1989, POLYM HDB
  • [6] KINETICS OF CRYSTALLIZATION AND MELTING BEHAVIOR OF POLY(ETHYLENE NAPHTHALENE-2,6-DICARBOXYLATE)
    BUCHNER, S
    WISWE, D
    ZACHMANN, HG
    [J]. POLYMER, 1989, 30 (03) : 480 - 488
  • [7] CATTRON WW, 1997, Patent No. 5646208
  • [8] BLOCK COPOLYMERS - COPOLYMERIZATION OF ETHYLENE TEREPHTHALATE AND POLYOXYETHYLENE GLYCOLS
    COLEMAN, D
    [J]. JOURNAL OF POLYMER SCIENCE, 1954, 14 (73): : 15 - 28
  • [9] DAUBENY RD, 1954, PROC R SOC LON SER-A, V226, P531
  • [10] DeAraujo MS, 1996, J APPL POLYM SCI, V60, P2437
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