The Actual Active Species of Sulfur-Modified Gold-Supported Palladium as a Highly Effective Palladium Reservoir in the Suzuki-Miyaura Coupling

被引：34

作者：

Hoshiya, Naoyuki ^{[1
,2
]}

Shuto, Satoshi ^{[1
]}

Arisawa, Mitsuhiro ^{[1
]}

机构：

[1] Hokkaido Univ, Fac Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan

[2] Furuya Met Co Ltd, Tokyo 1700005, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 05期

基金：

日本科学技术振兴机构;

关键词：

C-C coupling; combinatorial chemistry; green chemistry; heterogeneous catalysis; palladium; HETEROGENEOUS CATALYSIS; HECK; METAL; PD;

D O I：

10.1002/adsc.201000820

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The actual active species of the recently developed sulfur-modified, gold-supported palladium material, S-modified Au-supported Pd (SAPd), with one of the lowest Pd-releasing levels and high recyclability in the Suzuki-Miyaura coupling, was investigated. Also, SAPd was found to work repeatedly as an excellent Pd reservoir for liquid-phase combinatorial synthesis.

引用

页码：743 / 748

页数：6

共 22 条

[1] Oxime carbapalladacycle covalently anchored to high surface area inorganic supports or polymers as heterogeneous green catalysts for the Suzuki reaction in water [J].

Baleizao, C ;

Corma, A ;

García, H ;

Leyva, A .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (02) :439-446

[2]

Briehn CA, 2001, ANGEW CHEM INT EDIT, V40, P4680, DOI 10.1002/1521-3773(20011217)40:24<4680::AID-ANIE4680>3.0.CO

[3]

2-X

[4] POLYMER-BOUND SUBSTRATES - A METHOD TO DISTINGUISH BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS [J].

COLLMAN, JP ;

KOSYDAR, KM ;

BRESSAN, M ;

LAMANNA, W ;

GARRETT, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) :2569-2579

[5] Suzuki-Miyaura cross-coupling with quasi-heterogeneous palladium [J].

Conlon, DA ;

Pipik, B ;

Ferdinand, S ;

LeBlond, CR ;

Sowa, JR ;

Izzo, B ;

Collins, P ;

Ho, GJ ;

Williams, JM ;

Shi, YJ ;

Sun, YK .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (08) :931-935

[6] Are heterogeneous catalysts precursors to homogeneous catalysts? [J].

Davies, IW ;

Matty, L ;

Hughes, DL ;

Reider, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (41) :10139-10140

[7] Palladium Nanoparticles in Allylic Alkylations and Heck Reactions: The Molecular Nature of the Catalyst Studied in a Membrane Reactor [J].

Dieguez, Montserrat ;

Pamies, Oscar ;

Mata, Yvette ;

Teuma, Emmanuelle ;

Gomez, Montserrat ;

Ribaudo, Fabrizio ;

van Leeuwen, Piet W. N. M. .

ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (16) :2583-2598

[8] Assessment of structural diversity in combinatorial synthesis [J].

Fergus, S ;

Bender, A ;

Spring, DR .

CURRENT OPINION IN CHEMICAL BIOLOGY, 2005, 9 (03) :304-309

[9] The art of meeting palladium specifications in active pharmaceutical ingredients produced by Pd-catalyzed reactions [J].

Garrett, CE ;

Prasad, K .

ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (08) :889-900

[10] Sulfur Modification of Au via Treatment with Piranha Solution Provides Low-Pd Releasing and Recyclable Pd Material, SAPd [J].

Hoshiya, Naoyuki ;

Shimoda, Masahiko ;

Yoshikawa, Hideki ;

Yamashita, Yoshiyuki ;

Shuto, Satoshi ;

Arisawa, Mitsuhiro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (21) :7270-+

← 1 2 3 →