Bioethanol Upgrading to Renewable Monomers Using Hierarchical Zeolites: Catalyst Preparation, Characterization, and Catalytic Studies

被引:8
作者
Iadrat, Ploychanok [1 ]
Wattanakit, Chularat [2 ]
机构
[1] Vidyasirimedhi Inst Sci & Technol, Sch Mol Sci & Engn, Rayong 21210, Thailand
[2] Vidyasirimedhi Inst Sci & Technol, Sch Energy Sci & Engn, Rayong 21210, Thailand
关键词
bioethanol upgrading; renewable monomers; hierarchical zeolites; light olefins; ETHANOL DEHYDRATION; ACID SITES; ELECTRIC VEHICLES; SURFACE-ACIDITY; ZSM-5; ZEOLITES; COKE FORMATION; MFI ZEOLITES; BIO-ETHANOL; CONVERSION; PERFORMANCE;
D O I
10.3390/catal11101162
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bioethanol is one of the most promising renewable resources for the production of important monomers. To date, there have been various processes proposed for bioethanol conversion to renewable monomers. In this review, the catalytic bioethanol upgrading to various types of monomers using hierarchical zeolites as catalysts is illustrated, including the recent design and preparation of hierarchical zeolites for these catalytic processes. The characterizations of catalysts including textural properties, pore architectures, acidic properties, and active species are also exemplified. Moreover, the catalytic studies with various processes of monomer production from bioethanol including bioethanol dehydration, bioethanol to hydrocarbons, and bioethanol to butadiene are revealed in terms of catalytic activities and mechanistic studies. In addition, the future perspectives of these catalytic circumstances are proposed in both economic and sustainable development contexts.
引用
收藏
页数:30
相关论文
共 50 条
  • [31] Synthesis and characterization of hierarchical Y zeolites using NH4HF2 as dealumination agent
    Feng, Aihu
    Yu, Yang
    Mi, Le
    Cao, Yunzhen
    Yu, Yun
    Song, Lixin
    MICROPOROUS AND MESOPOROUS MATERIALS, 2019, 280 : 211 - 218
  • [32] Catalytic Oxidation of Phenol over Zeolite Based Cu/Y-5 Catalyst: Part 1: Catalyst Preparation and Characterization
    Valkaj, K. Maduna
    Witinne, O.
    Katovic, A.
    KEMIJA U INDUSTRIJI-JOURNAL OF CHEMISTS AND CHEMICAL ENGINEERS, 2015, 64 (1-2): : 1 - 10
  • [33] Catalytic fast pyrolysis of cellulose in a microreactor system using hierarchical zsm-5 zeolites treated with various alkalis
    Qiao, Kai
    Shi, Xu
    Zhou, Feng
    Chen, Hao
    Fu, Jie
    Ma, Huixia
    Huang, He
    APPLIED CATALYSIS A-GENERAL, 2017, 547 : 274 - 282
  • [34] Preparation of bio-oil derived from catalytic upgrading of biomass vacuum pyrolysis vapor over metal-loaded HZSM-5 zeolites
    Li, Xiaohua
    Dong, Wenbin
    Zhang, Jin
    Shao, Shanshan
    Cai, Yixi
    JOURNAL OF THE ENERGY INSTITUTE, 2020, 93 (02) : 605 - 613
  • [35] Catalytic upgrading of heavy oil using NiCo/γ-Al2O3 catalyst: Effect of initial atmosphere and water-gas shift reaction
    Avbenake, Onoriode P.
    Al-Hajri, Rashid S.
    Jibril, Baba Y.
    FUEL, 2019, 235 : 736 - 743
  • [36] A novel route, using zeolites as the precursors, for the preparation of electronic ceramics, cordierite and β-spodumene and their characterization.
    Selvaraj, K
    Ramaswamy, V
    Ramaswamy, AV
    RECENT ADVANCES IN BASIC AND APPLIED ASPECTS OF INDUSTRIAL CATALYSIS, 1998, 113 : 623 - 630
  • [37] Characterization and Catalytic Performance in n-Hexane Cracking of HEU-1 Zeolites Dealuminated Using Hydrochloric Acid and Hydrothermal Treatments
    Liu Xiaoling
    Wang Yan
    Wang Xujin
    Zhang Yafei
    Gong Yanjun
    Xu Qinghu
    Xu Jun
    Deng Feng
    Dou Tao
    CHINESE JOURNAL OF CATALYSIS, 2012, 33 (12) : 1889 - 1900
  • [38] Synthesis of hierarchical Y and ZSM-5 zeolites using post-treatment approach to maximize catalytic cracking performance
    Talebian-Kiakalaieh, Amin
    Tarighi, Sara
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2020, 88 : 167 - 177
  • [39] Pyrolysis and catalytic upgrading of low-rank coal using a NiO/MgO-Al2O3 catalyst
    Li, Yi
    Amin, Muhammad Nadeem
    Lu, Xingmei
    Li, Chunshan
    Ren, Fuqiang
    Zhang, Suojiang
    CHEMICAL ENGINEERING SCIENCE, 2016, 155 : 194 - 200
  • [40] Preparation and Characterization of Multichannel Catalyst Monolith using ZSM-5 Zeolite
    Yunus, Sharifah Noor Munirah S. M.
    Ismail, Kamariah Noor
    Hamid, Ku Halim Ku
    Alias, Rusmi
    Musa, Mohibah
    Ramley, Muhd Hafiz
    Aziz, Dicky Zulkainey Abd
    2012 IEEE COLLOQUIUM ON HUMANITIES, SCIENCE & ENGINEERING RESEARCH (CHUSER 2012), 2012,