Bioethanol Upgrading to Renewable Monomers Using Hierarchical Zeolites: Catalyst Preparation, Characterization, and Catalytic Studies

被引:8
作者
Iadrat, Ploychanok [1 ]
Wattanakit, Chularat [2 ]
机构
[1] Vidyasirimedhi Inst Sci & Technol, Sch Mol Sci & Engn, Rayong 21210, Thailand
[2] Vidyasirimedhi Inst Sci & Technol, Sch Energy Sci & Engn, Rayong 21210, Thailand
关键词
bioethanol upgrading; renewable monomers; hierarchical zeolites; light olefins; ETHANOL DEHYDRATION; ACID SITES; ELECTRIC VEHICLES; SURFACE-ACIDITY; ZSM-5; ZEOLITES; COKE FORMATION; MFI ZEOLITES; BIO-ETHANOL; CONVERSION; PERFORMANCE;
D O I
10.3390/catal11101162
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bioethanol is one of the most promising renewable resources for the production of important monomers. To date, there have been various processes proposed for bioethanol conversion to renewable monomers. In this review, the catalytic bioethanol upgrading to various types of monomers using hierarchical zeolites as catalysts is illustrated, including the recent design and preparation of hierarchical zeolites for these catalytic processes. The characterizations of catalysts including textural properties, pore architectures, acidic properties, and active species are also exemplified. Moreover, the catalytic studies with various processes of monomer production from bioethanol including bioethanol dehydration, bioethanol to hydrocarbons, and bioethanol to butadiene are revealed in terms of catalytic activities and mechanistic studies. In addition, the future perspectives of these catalytic circumstances are proposed in both economic and sustainable development contexts.
引用
收藏
页数:30
相关论文
共 50 条
  • [1] Effects of zeolite frameworks and hierarchical structures on catalytic bioethanol dehydration: In-situ DRIFTS and DFT studies
    Iadrat, Ploychanok
    Yomthong, Krissanapat
    Rodaum, Chadatip
    Pornsetmetakul, Peerapol
    Thivasasith, Anawat
    Prasertsab, Anittha
    Fan, Xiaolei
    Sooknoi, Tawan
    Wattanakit, Chularat
    FUEL, 2023, 338
  • [2] Catalytic Upgrading of Lignocellulosic Biomass-Derived Compounds Using Hierarchical ZSM-5 Zeolites
    Vasconcelos, Sancler C.
    Rossa, Vinicius
    Quattrociocchi, Daniel G. S.
    Madriaga, Vinicius G. C.
    Ribeiro, Maria Clara O.
    Pinheiro, Saulo B.
    Santos, Rodrigo D. dos
    Archanjo, Braulio S.
    Urquieta-Gonzalez, Ernesto A.
    Soares, Andre V. H.
    Passos, Fabio B.
    Varma, Rajender S.
    Lima, Thiago M.
    ENERGY & FUELS, 2024, : 23823 - 23835
  • [3] Synthesis and Characterization of Hierarchical ZSM-5 Zeolites with Outstanding Mesoporosity and Excellent Catalytic Properties
    Song, Guoqiang
    Chen, Wenting
    Dang, Peipei
    Yang, Shengyuan
    Zhang, Yuan
    Wang, Yuanyi
    Xiao, Ruidi
    Ma, Rong
    Li, Fuxiang
    NANOSCALE RESEARCH LETTERS, 2018, 13
  • [4] Catalytic Upgrading of Coal Pyrolysis Gaseous Tar over Hierarchical Y-Type Zeolites Synthesized Using a Microwave Hydrothermal Method
    Lv, Peng
    Yan, Lunjing
    Liu, Yan
    Wang, Meijun
    Bao, Weiren
    Li, Fan
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (47) : 21817 - 21826
  • [5] Deactivation and regeneration dynamics in hierarchical zeolites: Coke characterization and impact on catalytic cracking of vacuum gas oil
    Fals, Jayson
    Ospina-Castro, Maria L.
    Ramos-Hernandez, Andrea
    Pacheco-Londono, Leonardo
    Bocanegra, Sonia
    HELIYON, 2024, 10 (18)
  • [6] Preparation of hierarchical HZSM-5 based sulfated zirconium solid acid catalyst for catalytic upgrading of pyrolysis vapors from lignite pyrolysis
    Yang, Zhen
    Cao, Jing-Pei
    Ren, Xue-Yu
    Zhao, Xiao-Yan
    Liu, Sheng-Nan
    Guo, Zhen-Xing
    Shen, Wen-Zhong
    Bai, Jin
    Wei, Xian-Yong
    FUEL, 2019, 237 : 1079 - 1085
  • [7] Preparation and characterization of biomass-based nanocatalyst for hydrolysis and fermentation of catalytic hydrolysate to bioethanol
    Rekha, B.
    Saravanathamizhan, R.
    BIOMASS CONVERSION AND BIOREFINERY, 2023, 13 (03) : 1601 - 1612
  • [8] Catalytic upgrading of renewable levulinic acid to ethyl levulinate biodiesel using dodecatungstophosphoric acid supported on desilicated H-ZSM-5 as catalyst
    Nandiwale, Kakasaheb Y.
    Sonar, Shilpa K.
    Niphadkar, Prashant S.
    Joshi, Praphulla N.
    Deshpande, Shilpa S.
    Patil, Vilas S.
    Bokade, Vijay V.
    APPLIED CATALYSIS A-GENERAL, 2013, 460 : 90 - 98
  • [9] Catalytic upgrading of renewable furfuryl alcohol to alkyl levulinates using AlCl3 as a facile, efficient, and reusable catalyst
    Peng, Lincai
    Gao, Xueying
    Chen, Keli
    FUEL, 2015, 160 : 123 - 131
  • [10] Catalytic dehydration of ethanol over hierarchical ZSM-5 zeolites: studies of their acidity and porosity properties
    Tarach, Karolina A.
    Tekla, Justyna
    Makowski, Waclaw
    Filek, Urszula
    Mlekodaj, Kinga
    Girman, Vladimir
    Choi, Minkee
    Gora-Marek, Kinga
    CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (10) : 3568 - 3584