Hydrogen-bonding organization of (4,4) coordination layers into a 3-D molecular architecture with channels clathrating guest molecules [Cu(tdc)(bpy)(H2O)](bpy) (tdc = thiophine-2,5-dicarboxylate; bpy=4,4′-bipyridine)

被引：68

作者：

Sun, XZ ^{[1
]}

Sun, YF ^{[1
]}

Ye, BH ^{[1
]}

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 11期

关键词：

copper; 4,4 '-bipyridine; thiophene-2,5-dicarboxylate; hydrogen-bonding interaction; guest molecules;

D O I：

10.1016/j.inoche.2003.08.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of Cu(OAC)(2).H2O with thiophene-2,5-dicarboxylic acid (H(2)tdc) and 4,4'-bipyridine (bpy) gave a copper(II) coordination polymer {[Cu(tdc)(bpy)(H2O)](bpy)}(n) (1), in which the (4,4) layers are assembled via strong hydrogen bonds between the aqua ligands and the uncoordinated carboxylate oxygen atoms into a porous 3-D molecular architecture with parallelogrammic channels. The guest bpy molecules reside in the channels, involving intermolecular C-H (. . .) N hydrogen bonds with the host framework, can be removed upon heating at reduced pressure. (C) 2003 Published by Elsevier B.V.

引用

页码：1412 / 1414

页数：3

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