Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal-organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles

被引：53

作者：

Falaise, Clement ^{[1
]}

Volkringer, Christophe ^{[1
,2
]}

Giovine, Raynald ^{[1
]}

Prelot, Benedicte ^{[3
]}

Huve, Marielle ^{[1
]}

Loiseau, Thierry ^{[1
]}

机构：

[1] Univ Lille, Unite Catalyse & Chim Solide, ENSCL, UMR CNRS 8181, Bat C7,BP 9010859652, Villeneuve Dascq, France

[2] Inst Univ France, 1 Rue Descartes, F-75231 Paris 05, France

[3] Univ Montpellier, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, ENSCM, Pl E Bataillon,Bat 15,Cc 1502, F-34095 Montpellier 5, France

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 36期

关键词：

FUNCTIONALIZED MESOPOROUS SILICA; URANIUM EXTRACTION; AQUEOUS-SOLUTIONS; HIGHLY EFFICIENT; ZEOLITIC MATERIALS; ACTIVATED CARBON; URANYL IONS; SORPTION; REMOVAL; ADSORPTION;

D O I：

10.1039/c7dt02155k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aluminium-based metal-organic framework MIL-100 was utilized for the capture of actinide ([UO2](2+), Th4+) and lanthanide (Nd3+) cations. The results indicate a very quick sorption process, leading to very high cation uptakes together with selectivity for Th4+.

引用

页码：12010 / 12014

页数：5

共 51 条

[1] ACTINIDE UPTAKE ONTO ZEOLITE-L AND SAPO-34 [J].

AMINI, S ;

DYER, A .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1994, 178 (02) :273-289

[2] Fukushima accident: What happened? [J].

Baba, M. .

RADIATION MEASUREMENTS, 2013, 55 :17-21

[3] Introduction of amino groups into acid-resistant MOFs for enhanced U(VI) sorption [J].

Bai, Zhi-Qiang ;

Yuan, Li-Yong ;

Zhu, Lin ;

Liu, Zhi-Rong ;

Chu, Sheng-Qi ;

Zheng, Li-Rong ;

Zhang, Jing ;

Chai, Zhi-Fang ;

Shi, Wei-Qun .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (02) :525-534

[4] Uranium removal from aqueous solutions using a raw and HDTMA-modified phillipsite-bearing tuff [J].

Bampaiti, A. ;

Misaelides, P. ;

Noli, F. .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2015, 303 (03) :2233-2241

[5] Potential of Metal-Organic Frameworks for Separation of Xenon and Krypton [J].

Banerjee, Debasis ;

Cairns, Amy J. ;

Liu, Jian ;

Motkuri, Radha K. ;

Nune, Satish K. ;

Fernandez, Carlos A. ;

Krishna, Rajamani ;

Strachan, Denis M. ;

Thallapally, Praveen K. .

ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (02) :211-219

[6] Fukushima deep in hot water [J].

Brumfiel, Geoff ;

Cyranoski, David .

NATURE, 2011, 474 (7350) :135-136

[7] Water Stability and Adsorption in Metal-Organic Frameworks [J].

Burtch, Nicholas C. ;

Jasuja, Himanshu ;

Walton, Krista S. .

CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612

[8] Highly porous and stable metal-organic frameworks for uranium extraction [J].

Carboni, Michael ;

Abney, Carter W. ;

Liu, Shubin ;

Lin, Wenbin .

CHEMICAL SCIENCE, 2013, 4 (06) :2396-2402

[9] Uranium trioxide behavior during electron energy loss spectroscopy analysis [J].

Degueldre, Claude ;

Alekseev, Evgeny V. .

RADIATION PHYSICS AND CHEMISTRY, 2015, 108 :7-12

[10] Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework [J].

Demir, Selvan ;

Brune, Nicholas K. ;

Van Humbeck, Jeffrey F. ;

Mason, Jarad A. ;

Plakhova, Tatiana V. ;

Wang, Shuao ;

Tian, Guoxin ;

Minasian, Stefan G. ;

Tyliszczak, Tolek ;

Yaita, Tsuyoshi ;

Kobayashi, Tohru ;

Kalmykov, Stepan N. ;

Shiwaku, Hideaki ;

Shuh, David K. ;

Long, Jeffrey R. .

ACS CENTRAL SCIENCE, 2016, 2 (04) :253-265

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