Thermodynamics of aluminum and manganese deoxidation equilibria in Fe-Ni and Fe-Cr alloys

被引：70

作者：

Ohta, H ^{[1
]}

Suito, H ^{[1
]}

机构：

[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

ISIJ INTERNATIONAL | 2003年 / 43卷 / 09期

关键词：

Al deoxidation; interaction coefficient; Mn distribution; iron-nickel alloy; iron-chromium alloy;

D O I：

10.2355/isijinternational.43.1301

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Aluminum deoxidation equilibrium and manganese distribution have been studied at 1 873 K in the equilibrium experiment between CaO-Al2O3 slags and Fe-10, 20, 40 and 60mass%Ni alloys or Fe-10, 20 and 40mass%Cr alloys containing Mn and Al. On the basis of these results, the effect of Ni or Cr on the activity coefficients of Al and Mn based on liquid iron is discussed and the interaction coefficient between Al and 0 in liquid iron has been estimated. Some experiments in which Fe-18mass%Cr-8mass%Ni alloy containing Al and Mn was equilibrated with CaO-Al2O3 slags have been carried out at 1 873 K. It was found that the observed values for the oxygen content and the Mn distribution ratio in Fe-18mass%Cr-8 mass%Ni alloy are in good agreement with the calculated values by using the activity coefficients of Al and Mn obtained in this study.

引用

页码：1301 / 1308

页数：8

共 30 条

[21] Activities in CaO-MgO-Al2O3 slags and deoxidation equilibria of Al, Mg, and Ca [J].

Ohta, H ;

Suito, H .

ISIJ INTERNATIONAL, 1996, 36 (08) :983-990

[22]

REIN RH, 1965, T METALL SOC AIME, V233, P415

[23]

Sakao H., 1962, J JPN I MET, V26, P236

[24]

Sakao H., 1962, J JPN I METALS, V26, P30

[25]

Sigworth G. K., 1974, Metal Science, V8, P298

[26]

Sigworth G.K., 1977, CAN METALL Q, V16, P104, DOI DOI 10.1179/CMQ.1977.16.1.104

[27]

SUITO H, 1984, T IRON STEEL I JPN, V24, P257

[28] ALUMINUM OXYGEN EQUILIBRIUM BETWEEN CAO-AL2O3 MELTS AND LIQUID-IRON [J].

SUITO, H ;

INOUE, H ;

INOUE, R .

ISIJ INTERNATIONAL, 1991, 31 (12) :1381-1388

[29]

Suzuki K., 1970, TETSU TO HAGANE, V56, P20

[30] Deoxidation equilibria of molten nickel by Mg-Al and Mn-Al [J].

Zhao, YH ;

Morita, K ;

Sano, N .

METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 1998, 29 (01) :197-203

← 1 2 3 →