Multi-walled carbon nanotubes for the immobilization of enzyme in glucose biosensors

被引:174
作者
Wang, SG
Zhang, Q
Wang, RL
Yoon, SF
Ahn, J
Yang, DJ
Tian, JZ
Li, JQ
Zhou, Q
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Ctr Microelect, Singapore 639798, Singapore
[2] Natl Univ Singapore, Dept Community Occupat & Family Med, Singapore 119260, Singapore
关键词
carbon nanotubes; biosensor; enzyme immobilization; glucose; glucose oxidase;
D O I
10.1016/j.elecom.2003.07.007
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A novel biosensor, comprised of electrode of gold/multi-walled carbon nanotubes-glucose oxidase (Au/MWNTs-GOD), has been developed. The MWNTs were produced by microwave plasma enhanced chemical vapor deposition. The enzyme of GOD was immobilized using MWNTs. Performance and characteristics of the fabricated glucose biosensor were assessed with respect to response time, detection limit, pH value and storage stability. The results show that the fabricated biosensor is sensitive and stable in detecting glucose, indicating that MWNTs are a good candidate material for the immobilization of enzyme in glucose biosensor construction. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:800 / 803
页数:4
相关论文
共 17 条
[1]   Configurations used in the design of screen-printed enzymatic biosensors.: A review [J].
Albareda-Sirvent, M ;
Merkoçi, A ;
Alegret, S .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 69 (1-2) :153-163
[2]   Carbon nanotube electrode for oxidation of dopamine [J].
Britto, PJ ;
Santhanam, KSV ;
Ajayan, PM .
BIOELECTROCHEMISTRY AND BIOENERGETICS, 1996, 41 (01) :121-125
[3]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[4]   The immobilisation of proteins in carbon nanotubes [J].
Davis, JJ ;
Green, MLH ;
Hill, HAO ;
Leung, YC ;
Sadler, PJ ;
Sloan, J ;
Xavier, AV ;
Tsang, SC .
INORGANICA CHIMICA ACTA, 1998, 272 (1-2) :261-266
[5]   Immobilisation of glucose oxidase within metallic nanotubes arrays for application to enzyme biosensors [J].
Delvaux, M ;
Demoustier-Champagne, S .
BIOSENSORS & BIOELECTRONICS, 2003, 18 (07) :943-951
[6]   Glucose sensors based on glucose-oxidase-containing polypyrrole/aligned carbon nanotube coaxial nanowire electrodes [J].
Gao, M ;
Dai, L ;
Wallace, GG .
SYNTHETIC METALS, 2003, 137 (1-3) :1393-1394
[7]   Direct electron transfer of glucose oxidase on carbon nanotubes [J].
Guiseppi-Elie, A ;
Lei, CH ;
Baughman, RH .
NANOTECHNOLOGY, 2002, 13 (05) :559-564
[8]  
HARSANYI G, 2000, SENSORS BIOMEDICAL A
[9]   SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER [J].
IIJIMA, S ;
ICHIHASHI, T .
NATURE, 1993, 363 (6430) :603-605
[10]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58