One-dimensional co-crystallized coordination polymers showing reversible mechanochromic luminescence: cation-anion interaction directed rapid self-recovery

被引:52
作者
Yang, Yongsheng [1 ,2 ]
Fang, Xiaoyu [1 ]
Zhao, Si-Si [2 ]
Bai, Fengyang [2 ]
Zhao, Zhen [2 ]
Wang, Ke-Zhi [1 ]
Yan, Dongpeng [1 ,3 ]
机构
[1] Beijing Normal Univ, Coll Chem, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China
[2] Shenyang Normal Univ, Coll Chem & Chem Engn, Inst Catalysis Energy & Environm, Shenyang 110034, Peoples R China
[3] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金;
关键词
PIEZOCHROMIC LUMINESCENCE; AGGREGATION; DESIGN; GAP;
D O I
10.1039/c9cc09806b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three one-dimensional (1D) chain polymers (1D-9HAC, 1D-Cd-9AC, and 1D-Cd-9AC-HBIM) that exhibit different intermolecular interactions and stacking patterns have been designed and synthesized. Only 1D-Cd-9AC-HBIM with rigid (anion) and flexible (cation) units alternately arranged exhibits mechanochromic luminescence, which can be recovered through rapid solvent treatment or a self-recovery process.
引用
收藏
页码:5267 / 5270
页数:4
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