Effects of Methyl Substitution in Ruthenium Tris(2-pyridylmethyl)amine Photocaging Groups for Nitriles

被引：25

作者：

Arora, Karan ^{[1
]}

White, Jessica K. ^{[2
]}

Sharma, Rajgopal ^{[1
]}

Mazumder, Shivnath ^{[1
]}

Martin, Philip D. ^{[1
]}

Schlegel, H. Bernhard ^{[1
]}

Turro, Claudia ^{[2
]}

Kodanko, Jeremy J. ^{[1
,3
]}

机构：

[1] Wayne State Univ, Dept Chem, 5101 Cass Ave, Detroit, MI 48202 USA

[2] Ohio State Univ, Dept Chem & Biochem, Columbus, OH 43210 USA

[3] Barbara Ann Karmanos Canc Inst, Detroit, MI 48201 USA

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 14期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

COUPLED ELECTRON-TRANSFER; LIGAND-EXCHANGE; HYDROCARBON OXYGENATION; PYRIDYLAMINE COMPLEXES; EXCITATION-ENERGIES; ORGANIC-COMPOUNDS; RU(II) COMPLEXES; WATER OXIDATION; DENSITY; MONONUCLEAR;

D O I：

10.1021/acs.inorgchem.6b00650

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four complexes of the general formula [Ru(L)(CH3CN)(2)](PF6)(2), [L = TPA (5), MeTPA (6), Me(2)TPA (7), and Me(3)TPA (8)] [TPA = tris[(pyridin-2-yl)methyl]amine, where methyl groups were introduced consecutively onto the 6-position of py donors of TPA, were prepared and characterized by various spectroscopic techniques and mass spectrometry. While 5 and 8 were isolated as single stereoisomers, 6 and 7 were isolated as mixtures of stereoisomers in 2:1 and 1.5:1 ratios, respectively. Steric effects on ground state stability and thermal and photochemical reactivities were studied for all four complexes using H-1 NMR and electronic absorption spectroscopies and computational studies. These studies confirmed that the addition of steric bulk accelerates photochemical and thermal nitrile release.

引用

页码：6968 / 6979

页数：12

共 50 条

[21] Halogeno Ligand-Substitution Reactions of Ruthenium Complexes Bearing Ethylbis(2-pyridylmethyl)amine to Synthesize New Complexes
Misawa-Suzuki, Tomoyo
Tomioka, Nozomi
Osawa, Yutaro
Nagao, Hirotaka
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (37) : 4040 - 4047
[22] Syntheses and characterization of chloro(Me2SO)ruthenium(II) complexes with tris(2-pyridylmethyl)amine or N,N-bis(2-pyridylmethyl)glycinate and their application for catalytic hydroxylation of alkane
Yamaguchi, M
Kousaka, H
Yamagishi, T
CHEMISTRY LETTERS, 1997, (08) : 769 - 770
[23] A Novel Tetradentate Ruthenium(II) Complex Containing Tris(2-pyridylmethyl)amine (tpa) as an Inhibitor of Beta-Amyloid Fibrillation
Chan, Sharon Lai-Fung
Lu, Lihua
Lam, Tsz Lung
Yan, Siu-Cheong
Leung, Chung-Hang
Ma, Dik-Lung
CURRENT ALZHEIMER RESEARCH, 2015, 12 (05) : 434 - 438
[24] Tridentate coordination of monosubstituted derivatives of the tris(2-pyridylmethyl)amine ligand to FeCl3:: Structures and spectroscopic properties of ((2-bromopyridyl)methyl)bis(2-pyridylmethyl)amine FeIIICl3 and (((2-p-methoxyphenyl)pyridyl)methyl)Bis(2-pyridyl- methyl)]amine FeIIICl3 and comparison with the bis(2-pyridylmethyl)]amine FeIIICl3 complex
Mandon, D
Nopper, A
Litrol, T
Goetz, S
INORGANIC CHEMISTRY, 2001, 40 (18) : 4803 - 4806
[25] Mixed Multimetallic tris(2-pyridylmethyl)amine Based Complexes: Synthesis and Chiroptical Properties
Carmo dos Santos, Nadia Alessandra
Badetti, Elena
Begato, Federico
Wurst, Klaus
Licini, Giulia
Zonta, Cristiano
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 2021 (29) : 2942 - 2946
[26] Coordination and bioinorganic chemistry of aryl-appended tris(2-pyridylmethyl) amine ligands
Berreau, Lisa M.
COMMENTS ON INORGANIC CHEMISTRY, 2007, 28 (3-4) : 123 - 171
[27] Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes
Dahl, E. W.
Dong, H. T.
Szymczak, N. K.
CHEMICAL COMMUNICATIONS, 2018, 54 (08) : 892 - 895
[28] Synthesis and ethylene polymerization reactivity of chromium(II) and chromium(III) complexes incorporating pyridinebisimine, bis(2-pyridylmethyl)amine and tris(2-pyridylmethyl)amine ancillary ligands.
Carney, MJ
Robertson, NJ
Holman, DM
O'Rourke, CE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U132 - U132
[29] Synthesis and characterization of ruthenium(II) complexes bearing the bis(2-pyridylmethyl)amine ligand
Gibson, DH
Wu, JG
Mashuta, MS
INORGANICA CHIMICA ACTA, 2006, 359 (01) : 309 - 319
[30] [Bis(2-pyridylmethyl)amine]dichloridomercury(II)
Kim, Young-Inn
Lee, You-Soon
Seo, Hoe-Joo
Nam, Ki-Sun
Kang, Sung Kwon
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M358 - U762

← 1 2 3 4 5 →