Enhanced photocatalytic activity of nano-silica/copper plasmon by aminofunctional silane for dye pollutant degradation

The synthesis of silica gel nanostructures and loading it with copper specie via a hydrothermal process were performed. The sample is treated with an amino-functional reagent 3-aminopropyl triethoxysilane (APTES). The products were characterized by X-ray diffraction (XRD), FT-IR, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), TGA/DSC measurements, and X-ray photoelectron spectroscopy (XPS). The photocatalytic activities of the nanostructures were studied for degradation of methylene blue dye (as a classic dye contaminant) in aqueous solution utilizing visible light source. The results displayed that the sample treated with APTES is much more effective in photocatalytic degradation of methylene blue. This modified catalyst could eliminate methylene blue dye (50 mL, 18 mu g mL(-1)) within 60 min under visible light. The degradation efficiency was increased by shortening the degradation time to 30 min in the alkaline medium. The pseudo-first-order model well describes the kinetics of the reaction.