Porous Solids Arising from Synergistic and Competing Modes of Assembly: Combining Coordination Chemistry and Covalent Bond Formation

被引：27

作者：

Dutta, Ananya ^{[1
]}

Koh, Kyoungmoo ^{[1
]}

Wong-Foy, Antek G. ^{[1
]}

Matzger, Adam J. ^{[1
,2
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Dept Macromol Sci & Engn, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 13期

关键词：

coordination modes; covalent organic frameworks; crystal engineering; metal-organic frameworks; microporous materials; ORGANIC FRAMEWORKS; CRYSTALLINE;

D O I：

10.1002/anie.201411735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Design and synthesis of porous solids employing both reversible coordination chemistry and reversible covalent bond formation is described. The combination of two different linkage modes in a single material presents a link between two distinct classes of porous materials as exemplified by metal-organic frameworks (MOFs) and covalent organic frameworks (COFs). This strategy, in addition to being a compelling material-discovery method, also offers a platform for developing a fundamental understanding of the factors influencing the competing modes of assembly. We also demonstrate that even temporary formation of reversible connections between components may be leveraged to make new phases thus offering design routes to polymorphic frameworks. Moreover, this approach has the striking potential of providing a rich landscape of structurally complex materials from commercially available or readily accessible feedstocks.

引用

页码：3983 / 3987

页数：5

共 15 条

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