Lignin-Retaining Transparent Wood

被引:259
作者
Li, Yuanyuan [1 ]
Fu, Qiliang [1 ]
Rojas, Ramiro [1 ]
Yan, Min [2 ]
Lawoko, Martin [1 ]
Berglund, Lars [1 ]
机构
[1] KTH Royal Inst Technol, Chem Sci & Engn Inst, Dept Fibre & Polymer Technol, Wallenberg Wood Sci Ctr, Stockholm, Sweden
[2] KTH Royal Inst Technol, Sch Engn Sci, Isafjordsgatan 22, Stockholm, Sweden
基金
欧洲研究理事会;
关键词
building materials; delignification; energy saving; lignin; wood; PAPER; PULP; CHEMISTRY;
D O I
10.1002/cssc.201701089
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Optically transparent wood, combining optical and mechanical performance, is an emerging new material for light-transmitting structures in buildings with the aim of reducing energy consumption. One of the main obstacles for transparent wood fabrication is delignification, where around 30wt% of wood tissue is removed to reduce light absorption and refractive index mismatch. This step is time consuming and not environmentally benign. Moreover, lignin removal weakens the wood structure, limiting the fabrication of large structures. A green and industrially feasible method has now been developed to prepare transparent wood. Up to 80wt% of lignin is preserved, leading to a stronger wood template compared to the delignified alternative. After polymer infiltration, a high-lignin-content transparent wood with transmittance of 83%, haze of 75%, thermal conductivity of 0.23WmK(-1), and work-tofracture of 1.2MJm(-3) (a magnitude higher than glass) was obtained. This transparent wood preparation method is efficient and applicable to various wood species. The transparent wood obtained shows potential for application in energy-saving buildings.
引用
收藏
页码:3445 / 3451
页数:7
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