rac- and meso-3,3′-bis(3,5-dimethylphenyl)-3H,3′H-2,2′-biindenylidene-1,1′(2H,2′H)-dione

被引:5
作者
Ohba, S
Yamamoto, Y
Tanaka, K
机构
[1] Keio Univ, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238521, Japan
[2] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 7908577, Japan
关键词
D O I
10.1107/S0108270103010308
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the rac isomer of the title compound, C34H28O2, the two C-Ph-dimethylphenyl bond axes make an angle of 58.7 (1)degrees. There is no short contact between the two 3,5-dimethylphenyl rings, although the dihedral angle between them is 4.93 (7)degrees. The meso isomer has a center of symmetry at the middle of the C=C bond, and the two C-Ph-dimethylphenyl bond axes are antiparallel to one another.
引用
收藏
页码:O370 / O372
页数:3
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