Time-dependent fluctuations in single molecule spectroscopy: A generalized Wiener-Khintchine approach

被引：77

作者：

Barkai, E ^{[1
]}

Jung, Y ^{[1
]}

Silbey, R ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

PHYSICAL REVIEW LETTERS | 2001年 / 87卷 / 20期

关键词：

D O I：

10.1103/PhysRevLett.87.207403

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We consider the theory of time-dependent fluctuations in single molecule spectroscopy. In particular, the relation between stationary spectral diffusion processes and photon counting statistics is investigated. Within linear response theory, a general relation between Mandel's Q parameter and a three time dipole correlation function is obtained. For a prototype spectral diffusion process, an exact solution of Q is found which exhibits rich types of physical behaviors.

引用

收藏

页码：207403 / 1

页数：4

相关论文

共 24 条

[1] Exciton dynamics probed by single molecule spectroscopy [J].

Bach, H ;

Renn, A ;

Zumofen, G ;

Wild, UP .

PHYSICAL REVIEW LETTERS, 1999, 82 (10) :2195-2198

[2] Levy distribution of single molecule line shape cumulants in glasses [J].

Barkai, E ;

Silbey, R ;

Zumofen, G .

PHYSICAL REVIEW LETTERS, 2000, 84 (23) :5339-5342

[3] PHOTON ANTIBUNCHING IN THE FLUORESCENCE OF A SINGLE DYE MOLECULE TRAPPED IN A SOLID [J].

BASCHE, T ;

MOERNER, WE ;

ORRIT, M ;

TALON, H .

PHYSICAL REVIEW LETTERS, 1992, 69 (10) :1516-1519

[4] Are the spectral trails of single molecules consistent with the standard two-level system model of glasses at low temperatures? [J].

Boiron, AM ;

Tamarat, P ;

Lounis, B ;

Brown, R ;

Orrit, M .

CHEMICAL PHYSICS, 1999, 247 (01) :119-132

[5] Rabi resonances of a single molecule driven by rf and laser fields [J].

Brunel, C ;

Lounis, B ;

Tamarat, P ;

Orrit, M .

PHYSICAL REVIEW LETTERS, 1998, 81 (13) :2679-2682

[6] Nonclassical photon statistics in single-molecule fluorescence at room temperature [J].

Fleury, L ;

Segura, JM ;

Zumofen, G ;

Hecht, B ;

Wild, UP .

PHYSICAL REVIEW LETTERS, 2000, 84 (06) :1148-1151

[7] SPECTRAL DIFFUSION AND INDIVIDUAL 2-LEVEL SYSTEMS PROBED BY FLUORESCENCE OF SINGLE TERRYLENE MOLECULES IN A POLYETHYLENE MATRIX [J].

FLEURY, L ;

ZUMBUSCH, A ;

ORRIT, M ;

BROWN, R ;

BERNARD, J .

JOURNAL OF LUMINESCENCE, 1993, 56 (1-6) :15-28

[8] Theory of single-molecule optical line-shape distributions in low-temperature glasses [J].

Geva, E ;

Skinner, JL .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (44) :8920-8932

[9]

JUNG Y, IN PRESS ADV CHEM PH

[10]

KUBO R, 1962, FLUCTUATIONS RELAXAT