A simple one step synthesis of new 3,5-disubstituted-4-amino-1,2,4-triazoles

被引:111
作者
Bentiss, F
Lagrenée, M
Traisnel, M
Mernari, B
Elattari, H
机构
[1] Ecole Natl Super Chim Lille, Lab Cristallochim & Physicochim Solide, F-59652 Villeneuve Dascq, France
[2] Ecole Natl Super Chim Lille, Lab Physicochim Solides, F-59652 Villeneuve Dascq, France
[3] Univ Chouaib Doukkali, Fac Sci, Eljadida, Morocco
关键词
D O I
10.1002/jhet.5570360123
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A number of symmetrically 3,5-disubstituted 4-amino-1,2,4-triazoles have been prepared by the reaction of aromatic nitriles with hydrazine dihydrochloride or sulfate with an excess of hydrazine hydrate in ethylene or diethylene glycol under a nitrogen atmosphere. The structures of the new triazoles derivatives were confirmed by analytical and spectral data.
引用
收藏
页码:149 / 152
页数:4
相关论文
共 12 条
[1]  
ABDELRAHMAN MO, 1968, TETRAHEDRON LETT, V35, P3871
[2]   STUDIES ON SOME SYMMETRICALLY AND UNSYMMETRICALLY 3,6-DISUBSTITUTED 1,2-DIHYDRO-1,2,4,5-TETRAZINES INCLUDING THEIR CONVERSION INTO CORRESPONDING TETRAZINES AND 3,5-DISUBSTITUTED 4-AMINO-1,2,4-TRIAZOLES [J].
BOWIE, RA ;
NEILSON, DG ;
WATSON, KM ;
GARDNER, MD ;
RIDD, V ;
MAHMOOD, S .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (19) :2395-&
[3]  
Dallacker F., 1960, Monatsk. Chem., V91, P294
[4]  
FOHEY JL, 1970, J CHEM SOC C, P719
[5]   ORGANIC CHEMISTRY OF A NEW WEAK FIELD TRIDENTATE CHELATING AGENT . 3,5-DI(2-PYRIDYL)-1,2,4-TRIAZOLE [J].
GELDARD, JF ;
LIONS, F .
JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (01) :318-&
[6]  
KOTONE A, 1974, Patent No. 2248257
[7]  
KOTONE A, 1974, Patent No. 7430363
[8]   SYNTHESIS OF 3,5-BIS(M OR M,M'-DI-SUBSTITUTED-PARA-AMINOPHENYL)-N-AMINO-1,2,4-TRIAZOLE AND ITS APPLICATION TO BENZIDINE YELLOW TYPE PIGMENT [J].
MATSUKAWA, K ;
SETSUNE, J ;
TAKAGI, K ;
KITAO, T .
DYES AND PIGMENTS, 1982, 3 (04) :307-315
[9]   Announcements from the chemical institute of the University of Heidelberg. 159. The effect of dehydrated hydrazine from nitriles [J].
Muller, E ;
Herrdegen, L .
JOURNAL FUR PRAKTISCHE CHEMIE-LEIPZIG, 1921, 102 (4/7) :113-155
[10]  
PINNER A, 1894, CHEM BER, V27, P3273